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PhCH2OH..F anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-115.87kcal/molTherMihalick, Gatev, et al., 1996affinity derived using a ROH..F. neutral binding energy of 10.3 kcal/mol.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.040 ± 0.022LPDMihalick, Gatev, et al., 1996affinity derived using a ROH..F. neutral binding energy of 10.3 kcal/mol.
<3.050 ± 0.060PDMoylan, Dodd, et al., 1987 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mihalick, Gatev, et al., 1996
Mihalick, J.E.; Gatev, G.G.; Brauman, J.I., Electron Photodetachment Spectroscopy of Solvated Anions: RO.HF- or ROH.F-?, J. Am. Chem. Soc., 1996, 118, 49, 12424, https://doi.org/10.1021/ja954202k . [all data]

Moylan, Dodd, et al., 1987
Moylan, C.R.; Dodd, J.A.; Han, C.-C.; Brauman, J.I., Spectroscopy of Reactive Intermediates: Electron Photodetachment from Solvated Anions, J. Chem. Phys., 1987, 86, 10, 5350, https://doi.org/10.1063/1.452560 . [all data]


Notes

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