W(Cp)2(Cl)2


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas7.7 ± 1.2kcal/molReviewMartinho Simões 
Δfgas9.9 ± 2.0kcal/molReviewMartinho SimõesSelected data

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-17.3 ± 0.69kcal/molReviewMartinho Simões 
Δfsolid-15.1 ± 1.7kcal/molReviewMartinho SimõesSelected data
Quantity Value Units Method Reference Comment
Δcsolid-1479.8 ± 1.7kcal/molCC-RBMinas da Piedade, 1988Please also see Minas da Piedade, Shaofeng, et al., 1987.
Δcsolid-1477.4 ± 0.60kcal/molCC-SBTel'noi, Rabinovich, et al., 1976Please also see Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub25.0 ± 1.0kcal/molCC-SBTel'noi, Rabinovich, et al., 1976 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C12H16W (cr) + 2(Hydrogen chloride • 5.55Water) (solution) = C10H10Cl2W (cr) + 2Methane (g)

By formula: C12H16W (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2W (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Δr-40.61 ± 0.55kcal/molRSCCalado, Dias, et al., 1978Please also see Calhorda, Dias, et al., 1987.

C14H10F6O4W (cr) + 2(Hydrogen chloride • 4.40Water) (solution) = C10H10Cl2W (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6O4W (cr) + 2(HCl • 4.40H2O) (solution) = C10H10Cl2W (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Δr7.62 ± 0.45kcal/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.

C10H12W (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2W (cr) + 2Trichloromethane (l)

By formula: C10H12W (cr) + 2CCl4 (l) = C10H10Cl2W (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Δr-71.96 ± 0.81kcal/molRSCCalado, Dias, et al., 1979 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Minas da Piedade, 1988
Minas da Piedade, M.E., Tese de Doutoramento, Lisboa, 1988. [all data]

Minas da Piedade, Shaofeng, et al., 1987
Minas da Piedade, M.E.; Shaofeng, L.; Pilcher, G., J. Chem. Thermodyn., 1987, 19, 195. [all data]

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]

Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Organometal. Chem., 1979, 174, 77. [all data]


Notes

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