HBNH

Formula: BH₂N
Molecular weight: 26.834
CAS Registry Number: 15119-97-8
Information on this page:
Options:
- Switch to calorie-based units

Vibrational and/or electronic energy levels

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


Σ⁺	1	NH stretch	3710.5	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	1	NH stretch	3700.5	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	2	BH stretch	2775.3		Ar	IR	Thompson, Andrews, et al., 1995
	3	BN stretch	1786.19		gas	DL	Kawashima, Kawaguchi, et al., 1987
	3	BN stretch	1788.7	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	3	BN stretch	1782.8	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
Π	4	BH deform.	676.9		Ar	IR	Thompson, Andrews, et al., 1995
	4	BH deform.	671.6		Ar	IR	Thompson, Andrews, et al., 1995
	5	NH deform.	463.3	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	5	NH deform.	461.0	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995

Additional references: Jacox, 1994, page 137; Jacox, 1998, page 222; Baird and Datta, 1972; Armstrong and Clark, 1972

Notes

Medium

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Lory and Porter, 1973
Lory, E.R.; Porter, R.F., Infrared studies of matrix isolated species in the hydrogen-boron-nitrogen system, J. Am. Chem. Soc., 1973, 95, 6, 1766, https://doi.org/10.1021/ja00787a012 . [all data]

Thompson and Andrews, 1995
Thompson, C.A.; Andrews, L., Reactions of B Atoms with NH3 to Produce HBNH, BNBH, and B2N, J. Am. Chem. Soc., 1995, 117, 40, 10125, https://doi.org/10.1021/ja00145a029 . [all data]

Thompson, Andrews, et al., 1995
Thompson, C.A.; Andrews, L.; Martin, J.M.L.; El-Yazal, J., Infrared Spectra of Boron-Ammonia Reaction Products in Solid Argon, J. Phys. Chem., 1995, 99, 38, 13839, https://doi.org/10.1021/j100038a015 . [all data]

Kawashima, Kawaguchi, et al., 1987
Kawashima, Y.; Kawaguchi, K.; Hirota, E., Detection of HBNH by infrared diode laser spectroscopy, J. Chem. Phys., 1987, 87, 11, 6331, https://doi.org/10.1063/1.453462 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Baird and Datta, 1972
Baird, N.C.; Datta, R.K., Ab initio molecular orbital study of iminoborane, Inorg. Chem., 1972, 11, 1, 17, https://doi.org/10.1021/ic50107a004 . [all data]

Armstrong and Clark, 1972
Armstrong, D.R.; Clark, D.T., The electronic structures and energies of borazine, boronimide and dimeric boronimide, Theor. Chim. Acta, 1972, 24, 4, 307, https://doi.org/10.1007/BF01007549 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.