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Boron hydride oxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-47.400kcal/molReviewChase, 1998Data last reviewed in December, 1975
Quantity Value Units Method Reference Comment
gas,1 bar48.427cal/mol*KReviewChase, 1998Data last reviewed in December, 1975

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1200.1200. - 6000.
A 6.26322012.95350
B 9.7947611.209490
C -4.476131-0.291746
D 0.7589280.025885
E -0.033725-1.702441
F -49.77801-55.04661
G 53.0881059.00000
H -47.40019-47.40019
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1975 Data last reviewed in December, 1975

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Deltar360.5 ± 6.5kcal/molD-EAWenthold, Kim, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Deltar360.5 ± 6.5kcal/molD-EAWenthold, Kim, et al., 1997gas phase

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Pi 2 Bend 754.42 gas DL Butler
2 Bend 756.1 m Ar IR Lory and Porter, 1971
Ault, 1990
Andrews and Burkholder, 1991
Sigma+ 3 BO stretch 1825.56 gas DL Kawashima, Kawaguchi, et al., 1986
3 BO stretch 1822.3 s Ar IR Lory and Porter, 1971
Ault, 1990
Andrews and Burkholder, 1991

Additional references: Jacox, 1994, page 35; Jacox, 2003, page 32; Kawashima, Endo, et al., 1987; Kawashima, Endo, et al., 1989; Kawashima, Colarusso, et al., 1998

Notes

mMedium
sStrong

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Wenthold, Kim, et al., 1997
Wenthold, P.G.; Kim, J.B.; Jonas, K.-L.; Lineberger, W.C., An Experimental and Computational Study of the Electron Affinity of Boron Oxide, J. Phys. Chem. A, 1997, 101, 24, 4472, https://doi.org/10.1021/jp970645u . [all data]

Butler
Butler, J.E., unpublished data.. [all data]

Lory and Porter, 1971
Lory, E.R.; Porter, R.F., Infrared spectrum of matrix-isolated HBO, J. Am. Chem. Soc., 1971, 93, 23, 6301, https://doi.org/10.1021/ja00752a068 . [all data]

Ault, 1990
Ault, B.S., Matrix isolation study of excimer laser-induced photooxidation processes, J. Mol. Struct., 1990, 222, 1-2, 1, https://doi.org/10.1016/0022-2860(90)80002-2 . [all data]

Andrews and Burkholder, 1991
Andrews, L.; Burkholder, T.R., Infrared spectra of boron atom-water molecule reaction products trapped in solid argon, J. Phys. Chem., 1991, 95, 22, 8554, https://doi.org/10.1021/j100175a028 . [all data]

Kawashima, Kawaguchi, et al., 1986
Kawashima, Y.; Kawaguchi, K.; Hirota, E., Detection of HBO by discharge modulated infrared diode laser spectroscopy, Chem. Phys. Lett., 1986, 131, 3, 205, https://doi.org/10.1016/0009-2614(86)80546-2 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Kawashima, Endo, et al., 1987
Kawashima, Y.; Endo, Y.; Kawaguchi, K.; Hirota, E., Detection and equilibrium molecular structure of a short-lived molecule, HBO, by microwave spectroscopy, Chem. Phys. Lett., 1987, 135, 4-5, 441, https://doi.org/10.1016/0009-2614(87)85186-2 . [all data]

Kawashima, Endo, et al., 1989
Kawashima, Y.; Endo, Y.; Hirota, E., Microwave spectrum, molecular structure, and force field of HBO, J. Mol. Spectrosc., 1989, 133, 1, 116, https://doi.org/10.1016/0022-2852(89)90247-6 . [all data]

Kawashima, Colarusso, et al., 1998
Kawashima, Y.; Colarusso, P.; Zhang, K.Q.; Bernath, P.; Hirota, E., Infrared and Microwave Spectra and Force Field of DBO: The Coriolis Interaction between the «nu»1and «nu»2+ «nu»3States, J. Mol. Spectrosc., 1998, 192, 1, 152, https://doi.org/10.1006/jmsp.1998.7633 . [all data]


Notes

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