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vinylamine


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to C2H5N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)898.9kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity866.5kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.10ESTTakhistov and Ponomarev, 1994LL
8.20PEAlbercht, Allan, et al., 1984LBLHLM
8.6PEGonbeau, Lacombe, et al., 1988Vertical value; LL
8.65PEAlbercht, Allan, et al., 1984Vertical value; LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Takhistov and Ponomarev, 1994
Takhistov, V.V.; Ponomarev, D.A., Isodesmic reactions and thermochemistry of ions, Org. Mass Spectrom., 1994, 29, 395. [all data]

Albercht, Allan, et al., 1984
Albercht, B.; Allan, M.; Haselbach, E.; Neuhaus, L.; Carrupt, P.-A., 27. Molecular ions of transient species: Vinylamine-cation, Helv. Chim. Acta, 1984, 67, 220. [all data]

Gonbeau, Lacombe, et al., 1988
Gonbeau, D.; Lacombe, S.; Lasnes, M.; Ripoll, J.; Pfister-Guillouzo, G., Ethenylphosphine. Synthesis by flash-vacuum thermolysis and characterization by photoelectron spectroscopy, J. Am. Chem. Soc., 1988, 110, 2730. [all data]


Notes

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