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iron oxide

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to FeO+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)217.kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity210.4kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
1.49450 ± 0.00022ZEKEDrechsler, Boesl, et al., 1997B
1.492 ± 0.020LPESEngelking and Lineberger, 1977B
1.500 ± 0.040LPESWu, Desai, et al., 1996B
1.49303LPESAnderson, Lykke, et al., 1987B

Ionization energy determinations

IE (eV) Method Reference Comment
8.9 ± 0.16ENDArmentrout, Halle, et al., 1982LBLHLM
8.71 ± 0.10EIHildenbrand, 1975LLK
8. ± 1.EIBalducci, DeMaria, et al., 1971LLK


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Drechsler, Boesl, et al., 1997
Drechsler, G.; Boesl, U.; Bassmann, C.; Schlag, E.W., Mass selected anion-zero kinetic energy photoelectron spectroscopy (anion-ZEKE): Ground and low excited states of FeO, J. Chem. Phys., 1997, 107, 7, 2284-2291, https://doi.org/10.1063/1.474622 . [all data]

Engelking and Lineberger, 1977
Engelking, P.C.; Lineberger, W.C., Laser photoelecton spectrometry of FeO-: Electron affinity, electronic state separations, and ground state vibrations of iron oxide, and a new ground state assignment, J. Chem. Phys., 1977, 66, 5054. [all data]

Wu, Desai, et al., 1996
Wu, H.; Desai, R.; Wang, L.-S., Observation and Photoelectron Spectroscopic Study of Novel Mono- and Di-iron Oxide Molecules: FeOy- (y=1-4) and Fe2Oy- (y=1-5), J. Am. Chem. Soc., 1996, 118, 22, 5296, https://doi.org/10.1021/ja954153b . [all data]

Anderson, Lykke, et al., 1987
Anderson, T.; Lykke, K.R.; Neumark, D.M.; Lineberger, W.C., Autodetachment Study of the Electronic Spectroscopy of FeO-, J. Chem. Phys., 1987, 86, 4, 1858, https://doi.org/10.1063/1.452137 . [all data]

Armentrout, Halle, et al., 1982
Armentrout, P.B.; Halle, L.F.; Beauchamp, J.L., Reaction of Cr+, Mn+, Fe+, Co+, and Ni+ with O2 and N2O. Examination of the translational energy dependence of the cross sections of endothermic reactions, J. Chem. Phys., 1982, 76, 2449. [all data]

Hildenbrand, 1975
Hildenbrand, D.L., Thermochemistry of molecular FeO, FeO+ and FeO2, Chem. Phys. Lett., 1975, 34, 352. [all data]

Balducci, DeMaria, et al., 1971
Balducci, G.; DeMaria, G.; Guido, M.; Piacente, V., Dissociation energy of FeO, J. Chem. Phys., 1971, 55, 2596. [all data]


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