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Tetrachloroethylene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil394.2 ± 0.4KAVGN/AAverage of 14 out of 15 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus250.97KN/ADreisbach and Martin, 1949Uncertainty assigned by TRC = 0.05 K; TRC
Tfus250.6KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Ttriple250.81KN/ANovoselova, Rabinovich, et al., 1986Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc620.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap39.72kJ/molN/AMajer and Svoboda, 1985 
Deltavap39.72 ± 0.05kJ/molReviewManion, 2002weighted average of several measurements plus a correction for non-ideality; DRB
Deltavap39.7 ± 0.1kJ/molCMajer, Sváb, et al., 1980AC
Deltavap39.7 ± 0.84kJ/molVMathews, 1926Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 34.7 ± 0.1 kJ/mol; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
34.68394.1N/AMajer and Svoboda, 1985 
38.4322.N/ADejoz, Cruz Burguet, et al., 1995Based on data from 307. - 393. K.; AC
38.7325.AStephenson and Malanowski, 1987Based on data from 310. - 393. K. See also Boublík and Aim, 1972.; AC
38.9315.N/APolak, Murakami, et al., 1970Based on data from 300. - 380. K. See also Boublik, Fried, et al., 1984.; AC
37.6348.N/AFried, Gallant, et al., 1967Based on data from 333. - 373. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
301.03 - 380.844.180561440.819-49.171Polak, Murakami, et al., 1970Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
10.880250.81Novoselova, Rabinovich, et al., 1986, 2DH
10.88250.8Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
43.38250.81Novoselova, Rabinovich, et al., 1986, 2DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
3.9210.Domalski and Hearing, 1996CAL
43.38250.8

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.820125. - 210.crystaline, IIcrystaline, INovoselova, Rabinovich, et al., 1986, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
5.26125. - 210.crystaline, IIcrystaline, INovoselova, Rabinovich, et al., 1986, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Van de Vloed, 1939
Van de Vloed, A., Bull. Soc. Chim. Belg., 1939, 48, 229. [all data]

Novoselova, Rabinovich, et al., 1986
Novoselova, N.V.; Rabinovich, I.B.; Tsvetkova, L.Ya.; Moseeva, E.M.; Babinkov, A.G., Heat capacity and thermodynamic functions of tetrachloroethylene, Zh. Fiz. Khim., 1986, 60, 1627-30. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Majer, Sváb, et al., 1980
Majer, V.; Sváb, L.; Svoboda, V., Enthalpies of vaporization and cohesive energies for a group of chlorinated hydrocarbons, The Journal of Chemical Thermodynamics, 1980, 12, 9, 843-847, https://doi.org/10.1016/0021-9614(80)90028-2 . [all data]

Mathews, 1926
Mathews, J.H., The accurate measurement of heats of vaporization of liquids, J. Am. Chem. Soc., 1926, 48, 562-576. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Dejoz, Cruz Burguet, et al., 1995
Dejoz, Ana; Cruz Burguet, M.; Munoz, Rosa; Sanchotello, Margarita, Isobaric Vapor-Liquid Equilibria of Tetrachloroethylene with 1-Butanol and 2-Butanol at 6 and 20 kPa, J. Chem. Eng. Data, 1995, 40, 1, 290-292, https://doi.org/10.1021/je00017a064 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublík and Aim, 1972
Boublík, T.; Aim, K., Heats of vaporization of simple non-spherical molecule compounds, Collect. Czech. Chem. Commun., 1972, 37, 11, 3513-3521, https://doi.org/10.1135/cccc19723513 . [all data]

Polak, Murakami, et al., 1970
Polak, Jiri; Murakami, Sachio; Lam, V.T.; Benson, George C., Excess enthalpy, volume, and Gibbs free energy of cyclopentane-tetrachloroethylene mixtures at 25.deg., J. Chem. Eng. Data, 1970, 15, 2, 323-328, https://doi.org/10.1021/je60045a041 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Fried, Gallant, et al., 1967
Fried, Vojtech; Gallant, Paul; Schneier, Gary B., Vapor-liquid equilibrium in the system pyridine-tetrachloroethylene, J. Chem. Eng. Data, 1967, 12, 4, 504-508, https://doi.org/10.1021/je60035a011 . [all data]

Novoselova, Rabinovich, et al., 1986, 2
Novoselova, N.V.; Rabinovich, I.B.; Tsvetkova, L.Ya.; Moseeva, E.M.; Babinkov, A.G., Heat capacity and thermodynamic functions of tetrachloroethylene, Zhur. Fiz. Khim., 1986, 60, 1627-1630. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Phase change data, References