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Phosphorus monochloride monoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to ClOP+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
11.5EIBinnewies, 1983LBLHLM
11.7PEBinnewies, Solouki, et al., 1984Vertical value; LBLHLM
11.7PEBinnewies, Solouki, et al., 1984Vertical value; LBLHLM
11.85PEBerkosky, Ellison, et al., 1973Vertical value; LLK

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 PO stretch 1263.01 gas IR DL Allaf and Boustani, 1998
Bell, Hamilton, et al., 1998
Bell, Hamilton, et al., 2000
1 PO stretch 1258 vs Ar IR Binnewies, Lakenbrink, et al., 1983
Binnewies, Schnockel, et al., 1986
Schnockel and Schunck, 1987
2 Bend 308 w m Ar IR Binnewies, Lakenbrink, et al., 1983
3 PCl stretch 492 T gas IR Allaf and Boustani, 1998
3 PCl stretch 489 vs Ar IR Binnewies, Lakenbrink, et al., 1983
Binnewies, Schnockel, et al., 1986
Schnockel and Schunck, 1987

Additional references: Jacox, 1994, page 103; Jacox, 2003, page 142; Moores and Andrews, 1989; Brupbacher-Gatehouse and Brupbacher, 1999

Notes

wWeak
mMedium
vsVery strong
TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Binnewies, 1983
Binnewies, M., Bildung und stabilitat von gasformigem AsOCl und SbOCl massenspektrometrische untersuchungen, Z. Anorg. Allg. Chem., 1983, 505, 32. [all data]

Binnewies, Solouki, et al., 1984
Binnewies, M.; Solouki, B.; Bock, H.; Becherer, R.; Ahlrichs, R., O=P-Cl und S=P-Cl: Ionisation in der Gasphase, Angew. Chem., 1984, 96, 704. [all data]

Berkosky, Ellison, et al., 1973
Berkosky, J.L.; Ellison, F.O.; Lee, T.H.; Rabalais, J.W., Model for calculating spin-orbit interactions with applications to photoelectron spectroscopy, J. Chem. Phys., 1973, 59, 5342. [all data]

Allaf and Boustani, 1998
Allaf, A.W.; Boustani, I., Gas-phase infrared spectra of phosphorus (III) oxyhalide: Experimental and theoretical study of OPF and OPCl, Vib. Spectrosc., 1998, 16, 1, 69, https://doi.org/10.1016/S0924-2031(97)00047-7 . [all data]

Bell, Hamilton, et al., 1998
Bell, I.S.; Hamilton, P.A.; Davies, P.B., Infrared Laser Spectrum and Structure of Phosphoryl Chloride (ClPO) Formed at Ambient Temperature in the Gas Phase, J. Phys. Chem. A, 1998, 102, 45, 8836, https://doi.org/10.1021/jp983124v . [all data]

Bell, Hamilton, et al., 2000
Bell, I.S.; Hamilton, P.A.; Davies, P.B., The Diode--Laser Spectrum of Phosphoryl Chloride (ClPO), J. Mol. Spectrosc., 2000, 200, 2, 287, https://doi.org/10.1006/jmsp.2000.8058 . [all data]

Binnewies, Lakenbrink, et al., 1983
Binnewies, M.; Lakenbrink, M.; Schnockel, H., Z. Anorg. Allg. Chem., 1983, 497, 7. [all data]

Binnewies, Schnockel, et al., 1986
Binnewies, M.; Schnockel, H.; Gereke, R.; Schmutzler, R., «65533»ber die Bildung von Phosphor(III)-oxychlorid, POCl, durch Pyrolyse von Allyldichlorphosphit. Massenspektroskopische und Matrix-Infrarot-Untersuchungen, Z. Anorg. Allg. Chem., 1986, 534, 3, 143, https://doi.org/10.1002/zaac.19865340318 . [all data]

Schnockel and Schunck, 1987
Schnockel, H.; Schunck, S., Hochtemperaturhydrolyse von PCl3 und PBr3: IR-spektroskopischer Nachweis der matrixisolierten Molek«65533»le OPCl und OPBr, Z. Anorg. Allg. Chem., 1987, 548, 5, 161, https://doi.org/10.1002/zaac.19875480518 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Moores and Andrews, 1989
Moores, B.W.; Andrews, L., Oxidation of phosphorus(III) halides by red photolysis of ozone complexes in solid argon, J. Phys. Chem., 1989, 93, 5, 1902, https://doi.org/10.1021/j100342a041 . [all data]

Brupbacher-Gatehouse and Brupbacher, 1999
Brupbacher-Gatehouse, B.; Brupbacher, T., The molecular geometry, harmonic force field, bonding characteristics, and nuclear shielding parameters of OPCl, as determined from high resolution microwave spectra, J. Chem. Phys., 1999, 111, 14, 6300, https://doi.org/10.1063/1.479934 . [all data]


Notes

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