Perfluoroperoxide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil216.KN/AStreng, 1971Uncertainty assigned by TRC = 2. K; with decomposition
Quantity Value Units Method Reference Comment
Tfus109.7KN/AStreng, 1971Uncertainty assigned by TRC = 0.4 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
OF+17.5 ± 0.2OFEIMalone and McGee, 1965 
O2F+14.0 ± 0.1FEIMalone and McGee, 1966 
O2F+14.0 ± 0.1FEIMalone and McGee, 1965 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 17000 U gas Broderson, Frisch, et al., 1937

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a 1 OO stretch 1210 ± 3 gas IR Kim and Campbell, 1985
2 OF s-stretch 630 ± 3 gas IR Kim and Campbell, 1985
2 OF s-stretch 627 Ar IR Arkell, 1965
Gardiner, Lawrence, et al., 1971
Jacox, 1980
2 OF s-stretch 624 O2 IR Spratley, Turner, et al., 1966
3 Deform. 360 T gas IR Kim and Campbell, 1985
3 Deform. 366 Ar IR Gardiner, Lawrence, et al., 1971
3 Deform. 368 O2 IR Spratley, Turner, et al., 1966
4 Torsion 202 T gas IR Kim and Campbell, 1985
b 5 OF a-stretch 614 ± 3 gas IR Kim and Campbell, 1985
5 OF a-stretch 612 Ar IR Arkell, 1965
Gardiner, Lawrence, et al., 1971
Jacox, 1980
5 OF a-stretch 612 O2 IR Spratley, Turner, et al., 1966
6 Deform. 466 Ar IR Gardiner, Lawrence, et al., 1971
Jacox, 1980
6 Deform. 462 O2 IR Spratley, Turner, et al., 1966

Additional references: Jacox, 1994, page 225; Jackson, 1962

Notes

UUpper bound
TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Phase change data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Streng, 1971
Streng, A.G., Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature, J. Chem. Eng. Data, 1971, 16, 357. [all data]

Malone and McGee, 1965
Malone, T.J.; McGee, H.A., Jr., Mass spectrometric investigations of the synthesis, stability, and energetics of the low-temperature oxygen fluorides. I. Dioxygen difluoride, J. Phys. Chem., 1965, 69, 4338. [all data]

Malone and McGee, 1966
Malone, T.J.; McGee, H.A., Jr., Ionization potentials of the dioxygen fluoride free radical and the dioxygen difluoride molecule, J. Phys. Chem., 1966, 70, 316. [all data]

Broderson, Frisch, et al., 1937
Broderson, P.H.; Frisch, P.; Schumacher, H.-J., Z. Phys. Chem. B37, 1937, 25. [all data]

Kim and Campbell, 1985
Kim, K.C.; Campbell, G.M., The infrared spectrum and vibrational intensity of gaseous dioxygen difluoride (foof), J. Mol. Struct., 1985, 129, 3-4, 263, https://doi.org/10.1016/0022-2860(85)80170-8 . [all data]

Arkell, 1965
Arkell, A., None, J. Am. Chem. Soc., 1965, 87, 18, 4057, https://doi.org/10.1021/ja01096a006 . [all data]

Gardiner, Lawrence, et al., 1971
Gardiner, D.J.; Lawrence, N.J.; Turner, J.J., J. Chem. Soc. A, 1971, 400. [all data]

Jacox, 1980
Jacox, M.E., The reaction of F atoms with O2 in an argon matrix, J. Mol. Spectrosc., 1980, 84, 1, 74, https://doi.org/10.1016/0022-2852(80)90240-4 . [all data]

Spratley, Turner, et al., 1966
Spratley, R.D.; Turner, J.J.; Pimentel, G.C., Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding, J. Chem. Phys., 1966, 44, 5, 2063, https://doi.org/10.1063/1.1726981 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jackson, 1962
Jackson, R.H., J. Chem. Soc., 1962, 4585. [all data]


Notes

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