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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Carbon cation + carbon = (Carbon cation bullet carbon)

By formula: C+ + C = (C+ bullet C)

Quantity Value Units Method Reference Comment
Deltar619. ± 50.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet carbon) + carbon = (Carbon cation bullet 2carbon)

By formula: (C+ bullet C) + C = (C+ bullet 2C)

Quantity Value Units Method Reference Comment
Deltar774. ± 67.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 2carbon) + carbon = (Carbon cation bullet 3carbon)

By formula: (C+ bullet 2C) + C = (C+ bullet 3C)

Quantity Value Units Method Reference Comment
Deltar598.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 3carbon) + carbon = (Carbon cation bullet 4carbon)

By formula: (C+ bullet 3C) + C = (C+ bullet 4C)

Quantity Value Units Method Reference Comment
Deltar695.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 4carbon) + carbon = (Carbon cation bullet 5carbon)

By formula: (C+ bullet 4C) + C = (C+ bullet 5C)

Quantity Value Units Method Reference Comment
Deltar628.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 5carbon) + carbon = (Carbon cation bullet 6carbon)

By formula: (C+ bullet 5C) + C = (C+ bullet 6C)

Quantity Value Units Method Reference Comment
Deltar745.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 6carbon) + carbon = (Carbon cation bullet 7carbon)

By formula: (C+ bullet 6C) + C = (C+ bullet 7C)

Quantity Value Units Method Reference Comment
Deltar649.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M
Deltar523.kJ/molMIKESRadi, Rincon, et al., 1989gas phase; M

(Carbon cation bullet 7carbon) + carbon = (Carbon cation bullet 8carbon)

By formula: (C+ bullet 7C) + C = (C+ bullet 8C)

Quantity Value Units Method Reference Comment
Deltar753.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon cation bullet 8carbon) + carbon = (Carbon cation bullet 9carbon)

By formula: (C+ bullet 8C) + C = (C+ bullet 9C)

Quantity Value Units Method Reference Comment
Deltar703.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M
Deltar745. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase; M

(Carbon cation bullet 9carbon) + carbon = (Carbon cation bullet 10carbon)

By formula: (C+ bullet 9C) + C = (C+ bullet 10C)

Quantity Value Units Method Reference Comment
Deltar732. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase; M

Carbon anion + carbon = (Carbon anion bullet carbon)

By formula: C- + C = (C- bullet C)

Quantity Value Units Method Reference Comment
Deltar812. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet carbon) + carbon = (Carbon anion bullet 2carbon)

By formula: (C- bullet C) + C = (C- bullet 2C)

Quantity Value Units Method Reference Comment
Deltar628. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 2carbon) + carbon = (Carbon anion bullet 3carbon)

By formula: (C- bullet 2C) + C = (C- bullet 3C)

Quantity Value Units Method Reference Comment
Deltar703. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 3carbon) + carbon = (Carbon anion bullet 4carbon)

By formula: (C- bullet 3C) + C = (C- bullet 4C)

Quantity Value Units Method Reference Comment
Deltar630. ± 20.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 4carbon) + carbon = (Carbon anion bullet 5carbon)

By formula: (C- bullet 4C) + C = (C- bullet 5C)

Quantity Value Units Method Reference Comment
Deltar715.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 5carbon) + carbon = (Carbon anion bullet 6carbon)

By formula: (C- bullet 5C) + C = (C- bullet 6C)

Quantity Value Units Method Reference Comment
Deltar649.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 6carbon) + carbon = (Carbon anion bullet 7carbon)

By formula: (C- bullet 6C) + C = (C- bullet 7C)

Quantity Value Units Method Reference Comment
Deltar686.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 7carbon) + carbon = (Carbon anion bullet 8carbon)

By formula: (C- bullet 7C) + C = (C- bullet 8C)

Quantity Value Units Method Reference Comment
Deltar657.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 8carbon) + carbon = (Carbon anion bullet 9carbon)

By formula: (C- bullet 8C) + C = (C- bullet 9C)

Quantity Value Units Method Reference Comment
Deltar665.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(C3- bullet 4294967295carbon) + carbon = C3-

By formula: (C3- bullet 4294967295C) + C = C3-

Quantity Value Units Method Reference Comment
Deltar66.5 ± 8.4kJ/molN/AArnold, Bradforth, et al., 1991gas phase; Linear structure for both neutral and anion; B

(C4- bullet 4294967295carbon) + carbon = C4-

By formula: (C4- bullet 4294967295C) + C = C4-

Quantity Value Units Method Reference Comment
Deltar676. ± 15.kJ/molN/AArnold, Bradforth, et al., 1991gas phase; Linear structure for both anion and neutral. Bound state 37.063 kcal/mol up: Zhao, de Beer, et al., 1996; B

(C6- bullet 4294967295carbon) + carbon = C6-

By formula: (C6- bullet 4294967295C) + C = C6-

Quantity Value Units Method Reference Comment
Deltar-59. ± 24.kJ/molN/AArnold, Zhao, et al., 1992gas phase; There is a bound state at 47.107 kcal/mol up; Zhao, de Beer, et al., 1996; B

(C7- bullet 4294967295carbon) + carbon = C7-

By formula: (C7- bullet 4294967295C) + C = C7-

Quantity Value Units Method Reference Comment
Deltar478. ± 31.kJ/molN/AArnold, Bradforth, et al., 1991gas phase; Linear structure for both neutral and anion; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pargellis, 1990
Pargellis, A.N., Estimating Carbon Cluster Binding Energies from Measured Cn Distributions, n <= 10, J. Chem. Phys., 1990, 93, 3, 2099, https://doi.org/10.1063/1.459035 . [all data]

Radi, Rincon, et al., 1989
Radi, P.P.; Rincon, M.E.; Hsu, M.T.; Brodbelt-Lustig, J.; Kemper, P.; Bowers, M.T., Structure, Reactivity and Energetics of Covalently Bound Carbon Cluster Ions, C5+ to C11+: Experiment and Theory, J. Phys. Chem., 1989, 93, 16, 6187, https://doi.org/10.1021/j100353a045 . [all data]

Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M., Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211 . [all data]

Zhao, de Beer, et al., 1996
Zhao, Y.; de Beer, E.; Xu, C.; Taylor, T.; Neumark, D.M., Spectroscopy and Electron Detachment Dynamics of C4-, C6- and C8-, J. Chem. Phys., 1996, 105, 12, 4905, https://doi.org/10.1063/1.472341 . [all data]

Arnold, Zhao, et al., 1992
Arnold, C.C.; Zhao, Y.X.; Kitsopoulos, T.N.; Neumark, D.M., Study of C6(-) and C6 with Threshold Photodetachment Spectroscopy and Autodetachment Spectroscopy, J. Chem. Phys., 1992, 97, 9, 6121, https://doi.org/10.1063/1.463722 . [all data]


Notes

Go To: Top, Ion clustering data, References