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H3+


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H3+ + Argon = (H3+ bullet Argon)

By formula: H3+ + Ar = (H3+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar28.0 ± 0.8kJ/molPHPMSHiraoka and Mori, 1989gas phase
Deltar31. ± 3.kJ/molSIFTBedford and Smith, 1990gas phase; switching reaction(H3+)H2, Hiraoka and Mori, 1989
Quantity Value Units Method Reference Comment
Deltar56.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet Argon) + Argon = (H3+ bullet 2Argon)

By formula: (H3+ bullet Ar) + Ar = (H3+ bullet 2Ar)

Quantity Value Units Method Reference Comment
Deltar19.1 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar66.9J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet 2Argon) + Argon = (H3+ bullet 3Argon)

By formula: (H3+ bullet 2Ar) + Ar = (H3+ bullet 3Ar)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar72.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet 3Argon) + Argon = (H3+ bullet 4Argon)

By formula: (H3+ bullet 3Ar) + Ar = (H3+ bullet 4Ar)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar67.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet 4Argon) + Argon = (H3+ bullet 5Argon)

By formula: (H3+ bullet 4Ar) + Ar = (H3+ bullet 5Ar)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar69.9J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet 5Argon) + Argon = (H3+ bullet 6Argon)

By formula: (H3+ bullet 5Ar) + Ar = (H3+ bullet 6Ar)

Quantity Value Units Method Reference Comment
Deltar9.1 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(H3+ bullet 6Argon) + Argon = (H3+ bullet 7Argon)

By formula: (H3+ bullet 6Ar) + Ar = (H3+ bullet 7Ar)

Quantity Value Units Method Reference Comment
Deltar6.5 ± 0.4kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase

H3+ + Hydrogen = (H3+ bullet Hydrogen)

By formula: H3+ + H2 = (H3+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar29. ± 2.kJ/molAVGN/AAverage of 4 out of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar72.8 - 72.8J/mol*KRNGN/ARange of 6 values; Individual data points

(H3+ bullet Hydrogen) + Hydrogen = (H3+ bullet 2Hydrogen)

By formula: (H3+ bullet H2) + H2 = (H3+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar14. ± 0.8kJ/molPHPMSHiraoka, 1987gas phase
Deltar13.kJ/molHPMSBeuhler, Ehrenson, et al., 1983gas phase
Deltar14.kJ/molHPMSBeuhler, Ehrenson, et al., 1983gas phase; deuterated
Deltar17.kJ/molPHPMSHiraoka and Kebarle, 1975gas phase
Deltar7.5kJ/molHPMSBennett and Field, 1972gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka, 1987gas phase
Deltar70.7J/mol*KHPMSBeuhler, Ehrenson, et al., 1983gas phase
Deltar67.4J/mol*KHPMSBeuhler, Ehrenson, et al., 1983gas phase; deuterated
Deltar82.8J/mol*KPHPMSHiraoka and Kebarle, 1975gas phase
Deltar45.2J/mol*KHPMSBennett and Field, 1972gas phase; Entropy change is questionable

(H3+ bullet 2Hydrogen) + Hydrogen = (H3+ bullet 3Hydrogen)

By formula: (H3+ bullet 2H2) + H2 = (H3+ bullet 3H2)

Quantity Value Units Method Reference Comment
Deltar13. ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Deltar16.kJ/molPHPMSHiraoka and Kebarle, 1975gas phase
Quantity Value Units Method Reference Comment
Deltar77.4J/mol*KPHPMSHiraoka, 1987gas phase
Deltar84.5J/mol*KPHPMSHiraoka and Kebarle, 1975gas phase

(H3+ bullet 3Hydrogen) + Hydrogen = (H3+ bullet 4Hydrogen)

By formula: (H3+ bullet 3H2) + H2 = (H3+ bullet 4H2)

Quantity Value Units Method Reference Comment
Deltar7.2 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Deltar10.kJ/molPHPMSHiraoka and Kebarle, 1975gas phase
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, 1987gas phase
Deltar80.8J/mol*KPHPMSHiraoka and Kebarle, 1975gas phase

(H3+ bullet 4Hydrogen) + Hydrogen = (H3+ bullet 5Hydrogen)

By formula: (H3+ bullet 4H2) + H2 = (H3+ bullet 5H2)

Quantity Value Units Method Reference Comment
Deltar6.9 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSHiraoka, 1987gas phase

(H3+ bullet 5Hydrogen) + Hydrogen = (H3+ bullet 6Hydrogen)

By formula: (H3+ bullet 5H2) + H2 = (H3+ bullet 6H2)

Quantity Value Units Method Reference Comment
Deltar6.4 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka, 1987gas phase

(H3+ bullet 6Hydrogen) + Hydrogen = (H3+ bullet 7Hydrogen)

By formula: (H3+ bullet 6H2) + H2 = (H3+ bullet 7H2)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KPHPMSHiraoka, 1987gas phase

(H3+ bullet 7Hydrogen) + Hydrogen = (H3+ bullet 8Hydrogen)

By formula: (H3+ bullet 7H2) + H2 = (H3+ bullet 8H2)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, 1987gas phase

(H3+ bullet 8Hydrogen) + Hydrogen = (H3+ bullet 9Hydrogen)

By formula: (H3+ bullet 8H2) + H2 = (H3+ bullet 9H2)

Quantity Value Units Method Reference Comment
Deltar2.6 ± 0.4kJ/molPHPMSHiraoka, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka, 1987gas phase

H3+ + Oxygen = (H3+ bullet Oxygen)

By formula: H3+ + O2 = (H3+ bullet O2)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; From thermochemical cycle(O2H+)O2
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; From thermochemical cycle(O2H+)O2

(H3+ bullet Oxygen) + Oxygen = (H3+ bullet 2Oxygen)

By formula: (H3+ bullet O2) + O2 = (H3+ bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar48.1kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; From thermochemical cycle(O2H+)O2
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; From thermochemical cycle(O2H+)O2

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Isotope Effect and Nature of Bonding in the Cluster Ions H3+(Ar)n and D3+(Ar)n, J. Chem. Phys., 1989, 91, 8, 4821, https://doi.org/10.1063/1.456720 . [all data]

Bedford and Smith, 1990
Bedford, D.K.; Smith, D., Variable-temperature selected ion flow tube studies of the reactions of Ar+, Ar2+ and ArHn+ (n=1-3) ions with H2, HD and D2 at 300 K and 80 K, Int. J. Mass Spectrom. Ion Proc., 1990, 98, 2, 179, https://doi.org/10.1016/0168-1176(90)85017-V . [all data]

Hiraoka, 1987
Hiraoka, K., A Determination of the Stabilities of H3+(H2)n with n=1-9 from Measurements of the gas-Phase Ion Equilibria H3+(H2)n-1 + H2 = H3+(H2)n, J. Chem. Phys., 1987, 87, 7, 4048, https://doi.org/10.1063/1.452909 . [all data]

Beuhler, Ehrenson, et al., 1983
Beuhler, R.J.; Ehrenson, S.; Friedman, L., Hydrogen Cluster Ion Equilibria, J. Chem. Phys., 1983, 79, 12, 5982, https://doi.org/10.1063/1.445781 . [all data]

Hiraoka and Kebarle, 1975
Hiraoka, K.; Kebarle, P., A Determination of the Stabilities of H5+, H7+, H9+, and H11+ from Measurement of the Gas Phase Ion Equilibria Hn+ + H2 = H(n + 2)+ (n = 3, 5, 7, 9), J. Chem. Phys., 1975, 62, 6, 2267, https://doi.org/10.1063/1.430751 . [all data]

Bennett and Field, 1972
Bennett, S.L.; Field, F.H., Reversible Reactions of Gaseous Ions. VII. The Hydrogen System, J. Am. Chem. Soc., 1972, 94, 25, 8669, https://doi.org/10.1021/ja00780a003 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]


Notes

Go To: Top, Ion clustering data, References