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c-(NO)2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 48800 gas Billingsley and Callear, 1971
Forte and van den Bergy, 1978

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 NO s-stretch 1868.25 gas IR Ra Dinerman and Ewing, 1970
Matsumoto, Ohshima, et al., 1990
Howard and McKellar, 1993
Dkhissi, Lacome, et al., 1999
Fernandez, Tejeda, et al., 1999
1 NO s-stretch 1867.2 Ne IR Jacox and Thompson, 1990
Kometer, Legay, et al., 1994
Legay and Legay-Sommaire, 1995
Andrews and Zhou, 1999
1 NO s-stretch 1863.4 m Ar IR Fateley, Bent, et al., 1959
Krim and Lacome, 1998
1 NO s-stretch 1867.0 N2 IR Guillory and Hunter, 1969
Legay and Legay-Sommaire, 1995
Krim, 1998
1 NO s-stretch 1862 m CO2 IR Ra Fateley, Bent, et al., 1959
Ohlsen and Laane, 1978
1 NO s-stretch 1866 NO IR Ra Durig and Griffin, 1976
Anderson and Lassier-Govers, 1977
Nour, Chen, et al., 1984
2 N..N stretch 239.36 gas IR East, McKellar, et al., 1998
McKellar and Watson, 1999
Fernandez, Tejeda, et al., 1999
2 N..N stretch 242.8 Ar IR Krim and Lacome, 1998
2 N..N stretch 244.5 N2 IR Krim, 1998
2 N..N stretch 262 CO2 Ra Ohlsen and Laane, 1978
2 N..N stretch 266 NO IR Ra Durig and Griffin, 1976
Anderson and Lassier-Govers, 1977
Nour, Chen, et al., 1984
3 NNO s-bend 134.50 gas IR Ra East, McKellar, et al., 1998
McKellar and Watson, 1999
Fernandez, Tejeda, et al., 1999
3 NNO s-bend 175.5 T Ar IR Krim and Lacome, 1998
a2 4 Torsion 117 T gas IR East, McKellar, et al., 1998
4 Torsion 97 T NO IR Ra Durig and Griffin, 1976
Anderson and Lassier-Govers, 1977
Nour, Chen, et al., 1984
b2 5 NO a-stretch 1789.09 gas IR DL Dinerman and Ewing, 1970
Menoux, Le Doucen, et al., 1984
Brechignac, De Benedictis, et al., 1985
Matsumoto, Ohshima, et al., 1990
Watson and McKellar, 1997
Dkhissi, Soulard, et al., 1997
5 NO a-stretch 1780.6 Ne IR Jacox and Thompson, 1990
Kometer, Legay, et al., 1994
Legay and Legay-Sommaire, 1995
Andrews and Zhou, 1999
5 NO a-stretch 1778.7 Ne IR Jacox and Thompson, 1990
Kometer, Legay, et al., 1994
Legay and Legay-Sommaire, 1995
Andrews and Zhou, 1999
5 NO a-stretch 1776.3 s Ar IR Fateley, Bent, et al., 1959
Krim and Lacome, 1998
5 NO a-stretch 1779.9 N2 IR Guillory and Hunter, 1969
Legay and Legay-Sommaire, 1995
Krim, 1998
5 NO a-stretch 1768 s CO2 IR Fateley, Bent, et al., 1959
5 NO a-stretch 1762 NO IR Ra Anderson and Lassier-Govers, 1977
Nour, Chen, et al., 1984
6 NNO a-bend 429.14 gas IR East, McKellar, et al., 1998

Additional references: Jacox, 1994, page 200; Jacox, 1998, page 254; Jacox, 2003, page 233; Western, Langridge-Smith, et al., 1981; Brookes, McKellar, et al., 1997

Notes

mMedium
sStrong
TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Billingsley and Callear, 1971
Billingsley, J.; Callear, A.B., Investigation of the 2050 «65533» system of the nitric oxide dimer, Trans. Faraday Soc., 1971, 67, 589, https://doi.org/10.1039/tf9716700589 . [all data]

Forte and van den Bergy, 1978
Forte, E.; van den Bergy, H., The heat of formation of the nitric oxide dimer and its UV spectrum, Chem. Phys., 1978, 30, 3, 325, https://doi.org/10.1016/0301-0104(78)87004-9 . [all data]

Dinerman and Ewing, 1970
Dinerman, C.E.; Ewing, G.E., Infrared Spectrum, Structure, and Heat of Formation of Gaseous (NO)2, J. Chem. Phys., 1970, 53, 2, 626, https://doi.org/10.1063/1.1674038 . [all data]

Matsumoto, Ohshima, et al., 1990
Matsumoto, Y.; Ohshima, Y.; Takami, M., Mode-specific infrared photodissociation of nitric oxide dimers: High-resolution infrared spectroscopy of (14NO)2 and (15NO)2, J. Chem. Phys., 1990, 92, 2, 937, https://doi.org/10.1063/1.458076 . [all data]

Howard and McKellar, 1993
Howard, B.J.; McKellar, A.R.W., The, Mol. Phys., 1993, 78, 1, 55, https://doi.org/10.1080/00268979300100061 . [all data]

Dkhissi, Lacome, et al., 1999
Dkhissi, A.; Lacome, N.; Perrin, A., The NO Dimer, J. Mol. Spectrosc., 1999, 194, 2, 156, https://doi.org/10.1006/jmsp.1998.7780 . [all data]

Fernandez, Tejeda, et al., 1999
Fernandez, J.M.; Tejeda, G.; Ramos, A.; Howard, B.J.; Montero, S., Gas-Phase Raman Spectrum of NO Dimer, J. Mol. Spectrosc., 1999, 194, 2, 278, https://doi.org/10.1006/jmsp.1998.7797 . [all data]

Jacox and Thompson, 1990
Jacox, M.E.; Thompson, W.E., The vibrational spectra of molecular ions isolated in solid neon. IV. NO+, NO-, ONNO+, and ONNO-, J. Chem. Phys., 1990, 93, 11, 7609, https://doi.org/10.1063/1.459392 . [all data]

Kometer, Legay, et al., 1994
Kometer, R.; Legay, F.; Legay-Sommaire, N.; Schwentner, N., Vibrational spectroscopy of NO and (NO)2 isolated in solid neon, J. Chem. Phys., 1994, 100, 12, 8737, https://doi.org/10.1063/1.466728 . [all data]

Legay and Legay-Sommaire, 1995
Legay, F.; Legay-Sommaire, N., Infrared spectroscopy, infrared photoconversion, and ultraviolet photodissociation of NO dimers in neon and nitrogen matrices, J. Chem. Phys., 1995, 102, 20, 7798, https://doi.org/10.1063/1.469033 . [all data]

Andrews and Zhou, 1999
Andrews, L.; Zhou, M., Infrared spectra of (NO)[sub 2][sup -] and (NO)[sub 2][sup +] isomers trapped in solid neon, J. Chem. Phys., 1999, 111, 13, 6036, https://doi.org/10.1063/1.479900 . [all data]

Fateley, Bent, et al., 1959
Fateley, W.G.; Bent, H.A.; Crawford, B., Jr., Infrared Spectra of the Frozen Oxides of Nitrogen, J. Chem. Phys., 1959, 31, 1, 204, https://doi.org/10.1063/1.1730296 . [all data]

Krim and Lacome, 1998
Krim, L.; Lacome, N., The NO Dimer,, J. Phys. Chem. A, 1998, 102, 13, 2289, https://doi.org/10.1021/jp9733274 . [all data]

Guillory and Hunter, 1969
Guillory, W.A.; Hunter, C.E., Infrared Spectrum of Matrix-Isolated (NO)2, J. Chem. Phys., 1969, 50, 8, 3516, https://doi.org/10.1063/1.1671577 . [all data]

Krim, 1998
Krim, L., The NO dimer, 14N and 15N isotopomers isolated in nitrogen matrix: a near, mid and far infrared study, J. Mol. Struct., 1998, 471, 1-3, 267, https://doi.org/10.1016/S0022-2860(98)00487-6 . [all data]

Ohlsen and Laane, 1978
Ohlsen, J.R.; Laane, J., Characterization of the asymmetric nitric oxide dimer O:N:O:N by resonance Raman and infrared spectroscopy, J. Am. Chem. Soc., 1978, 100, 22, 6948, https://doi.org/10.1021/ja00490a030 . [all data]

Durig and Griffin, 1976
Durig, J.R.; Griffin, M.G., The Raman spectra of (14NO)2 and (15NO)2 solids at 20 K, J. Raman Spectrosc., 1976, 5, 3, 273, https://doi.org/10.1002/jrs.1250050308 . [all data]

Anderson and Lassier-Govers, 1977
Anderson, A.; Lassier-Govers, B., Infrared and raman spectra of crystalline nitric oxide, Chem. Phys. Lett., 1977, 50, 1, 124, https://doi.org/10.1016/0009-2614(77)80694-5 . [all data]

Nour, Chen, et al., 1984
Nour, E.M.; Chen, L.-H.; Strube, M.M.; Laane, J., Raman spectra and force constants for the nitric oxide dimer and its isotopic species, J. Phys. Chem., 1984, 88, 4, 756, https://doi.org/10.1021/j150648a028 . [all data]

East, McKellar, et al., 1998
East, A.L.L.; McKellar, A.R.W.; Watson, J.K.G., The intermolecular vibrations of the NO dimer, J. Chem. Phys., 1998, 109, 11, 4378, https://doi.org/10.1063/1.477040 . [all data]

McKellar and Watson, 1999
McKellar, A.R.W.; Watson, J.K.G., The Far Infrared Spectrum of the NO Dimer, J. Mol. Spectrosc., 1999, 194, 2, 229, https://doi.org/10.1006/jmsp.1998.7798 . [all data]

Menoux, Le Doucen, et al., 1984
Menoux, V.; Le Doucen, R.; Haeusler, C.; Deroche, J.C., Etude à basse température dans l'infrarouge proche du dimère (NO), Can. J. Phys., 1984, 62, 4, 322, https://doi.org/10.1139/p84-048 . [all data]

Brechignac, De Benedictis, et al., 1985
Brechignac, Ph.; De Benedictis, S.; Halberstadt, N.; Whitaker, B.J.; Avrillier, S., Infrared absorption and predissociation of NO dimer, J. Chem. Phys., 1985, 83, 5, 2064, https://doi.org/10.1063/1.449348 . [all data]

Watson and McKellar, 1997
Watson, J.K.G.; McKellar, A.R.W., The v, Can. J. Phys., 1997, 75, 3, 181, https://doi.org/10.1139/p96-152 . [all data]

Dkhissi, Soulard, et al., 1997
Dkhissi, A.; Soulard, P.; Perrin, A.; Lacome, N., The NO Dimer, J. Mol. Spectrosc., 1997, 183, 1, 12, https://doi.org/10.1006/jmsp.1996.7249 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Western, Langridge-Smith, et al., 1981
Western, C.M.; Langridge-Smith, P.R.R.; Howard, B.J.; Novick, S.E., Molecular beam electric resonance spectroscopy of the nitric oxide dimer, Mol. Phys., 1981, 44, 1, 145, https://doi.org/10.1080/00268978100102341 . [all data]

Brookes, McKellar, et al., 1997
Brookes, M.D.; McKellar, A.R.W.; Amano, T., Millimeter-Wave Spectrum of the NO Dimer, J. Mol. Spectrosc., 1997, 185, 1, 153, https://doi.org/10.1006/jmsp.1997.7357 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References