Nitric acid

• Formula: HNO₃
• Molecular weight: 63.0128
• IUPAC Standard InChI: InChI=1S/HNO3/c2-1(3)4/h(H,2,3,4) Copy

  
• IUPAC Standard InChIKey: GRYLNZFGIOXLOG-UHFFFAOYSA-N Copy
• CAS Registry Number: 7697-37-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Br^- + HNO₃ = (Br^- • HNO₃)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (Br^- • HNO₃) + HNO₃ = (Br^- • 2HNO₃)

(HO₄S^- • ) +  = (HO₄S^- • 2)

By formula: (HO₄S^- • HNO₃) + HNO₃ = (HO₄S^- • 2HNO₃)

Free energy of reaction

(HO₄S^- • 2) +  = (HO₄S^- •  • 2)

By formula: (HO₄S^- • 2H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 3) +  = (HO₄S^- •  • 3)

By formula: (HO₄S^- • 3H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 3H₂O₄S)

Free energy of reaction

( • ) +  = ( •  • )

By formula: (NO₃^- • HBr) + HNO₃ = (NO₃^- • HNO₃ • HBr)

 +  = ( • )

By formula: NO₃^- + HNO₃ = (NO₃^- • HNO₃)

( • ) +  = ( • 2)

By formula: (NO₃^- • HNO₃) + HNO₃ = (NO₃^- • 2HNO₃)

Free energy of reaction

( • 2) +  = ( • 3)

By formula: (NO₃^- • 2HNO₃) + HNO₃ = (NO₃^- • 3HNO₃)

Free energy of reaction

( • 3) +  = ( • 4)

By formula: (NO₃^- • 3HNO₃) + HNO₃ = (NO₃^- • 4HNO₃)

( • 4) +  = ( • 5)

By formula: (NO₃^- • 4HNO₃) + HNO₃ = (NO₃^- • 5HNO₃)

( • 5) +  = ( • 6)

By formula: (NO₃^- • 5HNO₃) + HNO₃ = (NO₃^- • 6HNO₃)

 +  = ( • )

By formula: Na⁺ + HNO₃ = (Na⁺ • HNO₃)

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO₃- and NO₃- association complexes with HNO₃ and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Wlodek, Luczynski, et al., 1980
Wlodek, S.; Luczynski, Z.; Wincel, H., Stabilities of gas-phase NO₃-.(HNO₃)n,n ≤ 6, clusters, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 39. [all data]

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H₂O and HNO_x clustering on NO_x-, J. Chem. Phys., 1980, 72, 1089. [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Fehsenfeld, Howard, et al., 1975
Fehsenfeld, F.C.; Howard, C.J.; Schmeltkopf, A.L., Gas Phase Ion Chemistry of HNO3, J. Chem. Phys., 1975, 63, 7, 2835, https://doi.org/10.1063/1.431722 . [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Notes

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• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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