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Phosphinous chloride, methylene-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.02PEBock and Bankmann, 1986Vertical value

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CH2 a-stretch 3095.6 w gas IR Ohno, Kurita, et al., 1987
2 CH2 s-stretch 2974.3 w gas IR Ohno, Kurita, et al., 1987
3 CH2 scissors 1372.3 m gas IR Ohno, Kurita, et al., 1987
4 C=P stretch 979.7 w gas IR Ohno, Kurita, et al., 1987
5 CH2 rock 792.4 s gas IR Ohno, Kurita, et al., 1987
6 PCl stretch 499.7 vs gas IR Ohno, Kurita, et al., 1987
7 PCCl deform. 340.2 w gas IR Ohno, Kurita, et al., 1987
a 8 CH2 wag 804.7 vs gas IR Ohno, Kurita, et al., 1987
9 Torsion 609.4 w gas IR Ohno, Kurita, et al., 1987

Additional references: Jacox, 1994, page 258; Kroto, Nixon, et al., 1984; Bak, Kristiansen, et al., 1982; Legon and Stephenson, 1991

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bock and Bankmann, 1986
Bock, H.; Bankmann, M., H3C-P=CH2: An ylide with two-Coordinate phosphorus?, Angew. Chem. Int. Ed. Engl., 1986, 25, 265. [all data]

Ohno, Kurita, et al., 1987
Ohno, K.; Kurita, E.; Kawamura, M.; Matsuura, H., Gas-phase infrared spectra of the unstable phosphaalkenes CF2:PH, CF2:PCF3, and CH2:PC: the C:P stretching vibration and force constant, J. Am. Chem. Soc., 1987, 109, 19, 5614, https://doi.org/10.1021/ja00253a009 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Kroto, Nixon, et al., 1984
Kroto, H.W.; Nixon, J.F.; Ohashi, O.; Ohno, K.; Simmons, N.P.C., The microwave spectrum 1-chlorophosphaethene, CH2«58875»PCl, J. Mol. Spectrosc., 1984, 103, 1, 113, https://doi.org/10.1016/0022-2852(84)90151-6 . [all data]

Bak, Kristiansen, et al., 1982
Bak, B.; Kristiansen, N.A.; Svanholf, H., Microwave Spectra and Structure of Six Isotopic Species of 1-Chlorophosphaethene, CH2 = PCl., Acta Chem. Scand. A, 1982, 36, 1, https://doi.org/10.3891/acta.chem.scand.36a-0001 . [all data]

Legon and Stephenson, 1991
Legon, A.C.; Stephenson, D., J. Chem. Soc., 1991, Faraday Trans. 87, 3325. [all data]


Notes

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