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FCP+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 56960 ± 320 gas Kroto, Nixon, et al., 1978

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 24077.7 ± 0.6 gas A-X 395 485 Kroto, Nixon, et al., 1978
King, Klapstein, et al., 1984


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CP stretch 1866 ± 2 gas EF King, Klapstein, et al., 1984
3 CF stretch 817 ± 2 gas EF King, Klapstein, et al., 1984

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CP stretch 1729 ± 2 gas PE EF Kroto, Nixon, et al., 1978
King, Klapstein, et al., 1984
3 CF stretch 765 ± 1 gas PE EF Kroto, Nixon, et al., 1978
King, Klapstein, et al., 1984

Additional references: Jacox, 1994, page 81

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kroto, Nixon, et al., 1978
Kroto, H.W.; Nixon, J.F.; Simmons, N.P.C.; Westwood, N.P.C., FC«equiv»P, C-fluorophosphaethyne: Preparation and detection by photoelectron and microwave spectroscopy, J. Am. Chem. Soc., 1978, 100, 446. [all data]

King, Klapstein, et al., 1984
King, M.A.; Klapstein, D.; Kroto, H.W.; Kuhn, R.; Maier, J.P.; Nixon, J.F., A 2«SIGMA»+ --> X 2«PI»i emission spectrum of the C-fluorophosphaethyne cation FCP+, J. Chem. Phys., 1984, 80, 6, 2332, https://doi.org/10.1063/1.446984 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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