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Trifluoromethyl cation


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 CF3 s-stretch 994 ± 16 gas TPE Dossmann (Soldi-Lose), Garcia, et al., 2012
a2 2 OPLA 809 ± 14 gas TPE Dossmann (Soldi-Lose), Garcia, et al., 2012
2 OPLA 798.1 Ne IR Forney, Jacox, et al., 1994
e' 3 CF stretch 1662.4 Ne IR Andrews, 1989
Forney, Jacox, et al., 1994
3 CF stretch 1667 Ar IR Prochaska and Andrews, 1978
Jacox, 1984
Halasinski, Godbout, et al., 1994

Additional references: Jacox, 1994, page 210; Jacox, 1998, page 258


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dossmann (Soldi-Lose), Garcia, et al., 2012
Dossmann (Soldi-Lose), H.; Garcia, G.A.; Nahon, L.; de Miranda, B.K.C.; Alcaraz, C., Comprehensive vacuum ultraviolet photoionization study of the CF3* trifluoromethyl radical using synchrotron radiation, J. Chem. Phys., 2012, 136, 20, 204304, https://doi.org/10.1063/1.4719529 . [all data]

Forney, Jacox, et al., 1994
Forney, D.; Jacox, M.E.; Irikura, K.K., Matrix isolation study of the interaction of excited neon atoms with CF4. Infrared spectra of CF+3 and CF-3, J. Chem. Phys., 1994, 101, 10, 8290, https://doi.org/10.1063/1.468094 . [all data]

Andrews, 1989
Andrews, L., Chemistry and Physics of Matrix-Isolated Species, L. Andrews and M. Moskovits, Eds., Elsevier, Amsterdam, 1989. [all data]

Prochaska and Andrews, 1978
Prochaska, F.T.; Andrews, L., Matrix photoionization studies of trifluoromethyl halide systems. Infrared spectra of the CF3+, CF2X+, and CF3X+ cations in solid argon, J. Am. Chem. Soc., 1978, 100, 7, 2102, https://doi.org/10.1021/ja00475a021 . [all data]

Jacox, 1984
Jacox, M.E., Matrix-isolation study of the decomposition of CF3NNCF3 by photons and by excited rare-gas atom bombardment at energies between 4.9 and 16.8 eV, Chem. Phys., 1984, 83, 1-2, 171, https://doi.org/10.1016/0301-0104(84)85231-3 . [all data]

Halasinski, Godbout, et al., 1994
Halasinski, T.M.; Godbout, J.T.; Allison, J.; Leroi, G.E., Infrared Detection of Matrix-Isolated, Mass-Selected Ions, J. Phys. Chem., 1994, 98, 15, 3930, https://doi.org/10.1021/j100066a004 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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