Methanimine


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH2N- + Hydrogen cation = Methanimine

By formula: CH2N- + H+ = CH3N

Quantity Value Units Method Reference Comment
Δr388.3 ± 5.1kcal/molG+TSKass and DePuy, 1985gas phase
Quantity Value Units Method Reference Comment
Δr381.0 ± 5.0kcal/molIMRBKass and DePuy, 1985gas phase

(CAS Reg. No. 54448-39-4 • 4294967295Methanimine) + Methanimine = CAS Reg. No. 54448-39-4

By formula: (CAS Reg. No. 54448-39-4 • 4294967295CH3N) + CH3N = CAS Reg. No. 54448-39-4

Quantity Value Units Method Reference Comment
Δr23.7 ± 4.1kcal/molN/AMacKay, Hemsworth, et al., 1976gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kass and DePuy, 1985
Kass, S.R.; DePuy, C.H., Gas phase ion chemistry of azides. The generation of CH=N- and CH2=NCH2-, J. Org. Chem., 1985, 50, 2874. [all data]

MacKay, Hemsworth, et al., 1976
MacKay, G.J.; Hemsworth, R.S.; Bohme, D.K., Absolute gas-phase acidities of CH3NH2, C2H5NH2, (CH3)2NH, and (CH3)3N, Can. J. Chem., 1976, 54, 1624. [all data]


Notes

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