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HCS+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CH stretch 3141.68 gas CC Rosenbaum, Owrutsky, et al., 1985
Rosenbaum, Owrutsky, et al., 1989
Pi 2 Bend 766.45 gas DL Davies and Rothwell, 1985

Additional references: Jacox, 1994, page 38; Jacox, 1998, page 145; Gudeman, Haese, et al., 1984; Bogey, Demuynck, et al., 1984; Tang and Saito, 1995; Margules, Lewen, et al., 2003


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rosenbaum, Owrutsky, et al., 1985
Rosenbaum, N.H.; Owrutsky, J.C.; Tack, L.M.; Saykally, R.J., Measurement of the «nu»1 vibration-rotation spectrum of the thioformyl ion (HCS+) by velocity modulation laser spectroscopy, J. Chem. Phys., 1985, 83, 10, 4845, https://doi.org/10.1063/1.449745 . [all data]

Rosenbaum, Owrutsky, et al., 1989
Rosenbaum, N.H.; Owrutsky, J.C.; Saykally, R.J., Velocity modulation infrared laser spectroscopy of HCS+: Analysis of hot bands and perturbations, J. Mol. Spectrosc., 1989, 133, 2, 364, https://doi.org/10.1016/0022-2852(89)90198-7 . [all data]

Davies and Rothwell, 1985
Davies, P.B.; Rothwell, W.J., Infrared laser spectroscopy of the «nu»2 mode of HCS+, J. Chem. Phys., 1985, 83, 4, 1496, https://doi.org/10.1063/1.449385 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Gudeman, Haese, et al., 1984
Gudeman, C.S.; Haese, N.H.; Piltch, N.D.; Woods, R.C., The observation of the J = 1-2 transition of HCS/+/ in a laboratory glow discharge, Astrophys. Lett., 1984, 246, L47, https://doi.org/10.1086/183550 . [all data]

Bogey, Demuynck, et al., 1984
Bogey, M.; Demuynck, C.; Destombes, J.L.; Lemoine, B., Millimeter wave spectrum of HCS+1, J. Mol. Spectrosc., 1984, 107, 2, 417, https://doi.org/10.1016/0022-2852(84)90019-5 . [all data]

Tang and Saito, 1995
Tang, J.; Saito, S., Microwave Spectra of the Isotopomers of HCS[TSUP]+[/TSUP] and Its Substitution Structure, Astrophys. J., 1995, 451, 2, L93, https://doi.org/10.1086/309694 . [all data]

Margules, Lewen, et al., 2003
Margules, L.; Lewen, F.; Winnewisser, G.; Botschwina, P.; Muller, H.S.P., The rotational spectrum up to 1 THz and the molecular structure of thiomethylium, HCS+, Phys. Chem. Chem. Phys., 2003, 5, 13, 2770, https://doi.org/10.1039/b303260d . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References