Bromo bis(N,N-diethyldithiocarbamate) iron (III)


Condensed phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
434.5298.095Yoshikawa, Sorai, et al., 1983T = 0.4 to 393 K. Unsmoothed experimental datum.

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
1.347crystaline, IVcrystaline, IIIYoshikawa, Sorai, et al., 1983Lambda type ferromagnetic transition.

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.09709.crystaline, IIIcrystaline, IIYoshikawa, Sorai, et al., 1983Schottky type anomaly. H and S values are the total of both transitions.
1.960265.7crystaline, IIcrystaline, IYoshikawa, Sorai, et al., 1983 

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
11.059.crystaline, IIIcrystaline, IIYoshikawa, Sorai, et al., 1983Schottky
7.51265.7crystaline, II, Noncrystaline, I, magnetic phase transitionYoshikawa, Sorai, et al., 1983 

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yoshikawa, Sorai, et al., 1983
Yoshikawa, M.; Sorai, M.; Suga, H.; Seki, S., Heat capacity of a five-coordinated iron(III) complex with spin S = 3/2, bromobis-(N,N-diethyldithiocarbamato)iron(III), between 0.4 and 300 K, J. Phys. Chem. Solids, 1983, 44, 311-321. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References