Bromo bis(N,N-diethyldithiocarbamate) iron (III)
- Formula: C10H20BrFeN2S4
- Molecular weight: 432.288
- CAS Registry Number: 54163-77-8
- Information on this page:
- Other data available:
- Options:
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Temperature of phase transition
| Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|
| 1.347 | crystaline, IV | crystaline, III | Yoshikawa, Sorai, et al., 1983 | Lambda type ferromagnetic transition. |
Enthalpy of phase transition
| ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 0.0232 | 9. | crystaline, III | crystaline, II | Yoshikawa, Sorai, et al., 1983 | Schottky type anomaly. H and S values are the total of both transitions. |
| 0.4685 | 265.7 | crystaline, II | crystaline, I | Yoshikawa, Sorai, et al., 1983 |
Entropy of phase transition
| ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 2.641 | 9. | crystaline, III | crystaline, II | Yoshikawa, Sorai, et al., 1983 | Schottky |
| 1.79 | 265.7 | crystaline, II, Non | crystaline, I, magnetic phase transition | Yoshikawa, Sorai, et al., 1983 |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Yoshikawa, Sorai, et al., 1983
Yoshikawa, M.; Sorai, M.; Suga, H.; Seki, S.,
Heat capacity of a five-coordinated iron(III) complex with spin S = 3/2, bromobis-(N,N-diethyldithiocarbamato)iron(III), between 0.4 and 300 K,
J. Phys. Chem. Solids, 1983, 44, 311-321. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Ttrs Temperature of phase transition ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.