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Bromo bis(N,N-diethyldithiocarbamate) iron (III)


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
103.8298.095Yoshikawa, Sorai, et al., 1983T = 0.4 to 393 K. Unsmoothed experimental datum.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
1.347crystaline, IVcrystaline, IIIYoshikawa, Sorai, et al., 1983Lambda type ferromagnetic transition.

Enthalpy of phase transition

DeltaHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.02329.crystaline, IIIcrystaline, IIYoshikawa, Sorai, et al., 1983Schottky type anomaly. H and S values are the total of both transitions.
0.4685265.7crystaline, IIcrystaline, IYoshikawa, Sorai, et al., 1983 

Entropy of phase transition

DeltaStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.6419.crystaline, IIIcrystaline, IIYoshikawa, Sorai, et al., 1983Schottky
1.79265.7crystaline, II, Noncrystaline, I, magnetic phase transitionYoshikawa, Sorai, et al., 1983 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yoshikawa, Sorai, et al., 1983
Yoshikawa, M.; Sorai, M.; Suga, H.; Seki, S., Heat capacity of a five-coordinated iron(III) complex with spin S = 3/2, bromobis-(N,N-diethyldithiocarbamato)iron(III), between 0.4 and 300 K, J. Phys. Chem. Solids, 1983, 44, 311-321. [all data]


Notes

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