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CS2+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Deltar17.5kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Deltar3.9kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar4.4kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.6kcal/molPIOno, Linn, et al., 1980gas phase

CS2+ + Carbonyl sulfide = (CS2+ bullet Carbonyl sulfide)

By formula: CS2+ + COS = (CS2+ bullet COS)

Quantity Value Units Method Reference Comment
Deltar5.8kcal/molPIOno, Osuch, et al., 1981gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CS2+ + Carbonyl sulfide = (CS2+ bullet Carbonyl sulfide)

By formula: CS2+ + COS = (CS2+ bullet COS)

Quantity Value Units Method Reference Comment
Deltar5.8kcal/molPIOno, Osuch, et al., 1981gas phase

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Deltar17.5kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar4.4kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Deltar3.9kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.6kcal/molPIOno, Linn, et al., 1980gas phase

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 49064 gas C-B 658 724 Frey, Gotchev, et al., 1978
Danis, Wyttenbach, et al., 1988
Evard, Wyttenbach, et al., 1989


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 652 ± 2 gas PI PE Frey, Gotchev, et al., 1978
Potts and Fattahallah, 1980
Kovac, 1983
1 Sym. stretch 652 ± 2 gas PF MP Danis, Wyttenbach, et al., 1988
Wang, Reutt, et al., 1988
Evard, Wyttenbach, et al., 1989
Baltzer, Wannberg, et al., 1996
Zhuang, Zhang, et al., 2006
Piu 2 Bend 348 ± 9 gas PF PE Danis, Wyttenbach, et al., 1988
Wang, Reutt, et al., 1988
Baltzer, Wannberg, et al., 1996
Zhuang, Zhang, et al., 2006
Sigmau+ 3 Asym. stretch 1024 ± 6 T gas PE Wang, Reutt, et al., 1988

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 35238.01 gas B-X 277 307 Callomon, 1958
Zhuang, Zhang, et al., 2006
To = 35270 Ne B-X Bondybey and English, 1980
To = 35226 Ne B-X Bondybey and English, 1980


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 613 gas PE MPD Balfour, 1976
Baltzer, Wannberg, et al., 1996
Zhuang, Zhang, et al., 2006
Piu 2 Bend 351 ± 5 gas PE Wang, Reutt, et al., 1988
Baltzer, Wannberg, et al., 1996
Zhuang, Zhang, et al., 2006
Sigmau+ 3 Asym. stretch 1320 ± 5 gas PE Wang, Reutt, et al., 1988
Baltzer, Wannberg, et al., 1996

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 20973.30 gas A-X 426 512 Balfour, 1976
Venkitachalam, 1999
He and Clouthier, 2006
To = 21010.6 Ne A-X 400 642 Bondybey, English, et al., 1979
Bondybey and English, 1980
Cheng, Lo, et al., 1995
Lorenz and Bondybey, 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 612.47 gas PE LF Liu, Hochlaf, et al., 2001
He and Clouthier, 2006
1 Sym. stretch 551 Ne LF Bondybey, English, et al., 1979
Bondybey and English, 1980
Zen and Lee, 1995
Lorenz and Bondybey, 2000
Piu 2 Bend («kappa» 2Su-) 510 ± 5 gas PE Liu, Hochlaf, et al., 2001
2 Bend (2Du,5/2) 286 ± 5 gas PE Liu, Hochlaf, et al., 2001
2 Bend 309 H Ne LF Bondybey, English, et al., 1979
Bondybey and English, 1980
Zen and Lee, 1995
Sigmau+ 3 Asym. stretch 1723 ± 5 gas PE Liu, Hochlaf, et al., 2001
3 Asym. stretch 1644 H Ne LF Bondybey and English, 1980

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 617 gas EM TPE Balfour, 1976
Fischer, Lochschmidt, et al., 1993
Huang, Cheung, et al., 1997
1 Sym. stretch 618 Ne LF Bondybey, English, et al., 1979
Bondybey and English, 1980
Cheng, Lo, et al., 1995
Zen and Lee, 1995
Piu 2 Bend 332 gas TPE Fischer, Lochschmidt, et al., 1993
Huang, Cheung, et al., 1997
2 Bend (2Du,5/2) 335.42 gas TPE LF Huang, Cheung, et al., 1997
He and Clouthier, 2006
2 Bend («mu» 2Su+) 328.79 gas TPE LF Huang, Cheung, et al., 1997
He and Clouthier, 2006
2 Bend 349 H Ne LF Bondybey, English, et al., 1979
Bondybey and English, 1980
Cheng, Lo, et al., 1995
Zen and Lee, 1995
Sigmau+ 3 Asym. stretch 1188 ± 8 gas EM PE Balfour, 1976
Wang, Reutt, et al., 1988
Baltzer, Wannberg, et al., 1996
3 Asym. stretch 1207.1 Ne LF IR Bondybey, English, et al., 1979
Bondybey and English, 1980
Cheng, Lo, et al., 1995
Zen and Lee, 1995
Halasinski, Godbout, et al., 1996
Zhou and Andrews, 2000
Lorenz and Bondybey, 2000
3 Asym. stretch 1200.5 Ar IR Zhou and Andrews, 2000

Additional references: Jacox, 1994, page 79; Jacox, 1998, page 186; Jacox, 2003, page 125; Smith, 1969; Eland, Devoret, et al., 1976; Maier and Thommen, 1980; Dunbar and Turner, 1981; Ibuki and Sugita, 1984

Notes

H(1/2)(2nu)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters, J. Chem. Phys., 1980, 73, 2523. [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2, J. Chem. Phys., 1981, 74, 1645. [all data]

Frey, Gotchev, et al., 1978
Frey, R.; Gotchev, B.; Peatman, W.B.; Pollak, H.; Schlag, E.W., Photoionization resonance study of the X(2«pi»), A(2«pi»), B(2«SIGMA»+) and C(2«SIGMA»+) states of CS2+ and COS+, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 137. [all data]

Danis, Wyttenbach, et al., 1988
Danis, P.O.; Wyttenbach, T.; Maier, J.P., Two-photon absorption spectroscopy of mass-selected ions: N2O+ and CS+2, J. Chem. Phys., 1988, 88, 6, 3451, https://doi.org/10.1063/1.453893 . [all data]

Evard, Wyttenbach, et al., 1989
Evard, D.D.; Wyttenbach, T.; Maier, J.P., Two-photon absorption spectroscopy of ion beams: carbon disulfide(1+) ~C2.SIGMA.g+ state characterization, J. Phys. Chem., 1989, 93, 9, 3522, https://doi.org/10.1021/j100346a032 . [all data]

Potts and Fattahallah, 1980
Potts, A.W.; Fattahallah, G.H., High-resolution ultraviolet photoelectron spectroscopy of CO2, COS and CS2, J. Phys. B:, 1980, 13, 2545. [all data]

Kovac, 1983
Kovac, B., The He i photoelectron spectra of CO2, CS2, and OCS: Vibronic coupling, J. Chem. Phys., 1983, 78, 4, 1684, https://doi.org/10.1063/1.444967 . [all data]

Wang, Reutt, et al., 1988
Wang, L.; Reutt, J.E.; Lee, Y.T.; Shirley, D.A., High resolution UV photoelectron spectroscopy of CO2, COS, and CS2 using supersonic molecular beams, J. Electron Spectrosc. Relat. Phenom., 1988, 47, 167. [all data]

Baltzer, Wannberg, et al., 1996
Baltzer, P.; Wannberg, B.; Lundqvist, M.; Karlsson, L.; Holland, D.M.P.; MacDonald, M.A.; Hayes, M.A.; Tomasello, P.; von Niessen, W., An experimental and theoretical study of the valence shell photoelectron spectrum of carbon disulphide, Chem. Phys., 1996, 202, 1, 185, https://doi.org/10.1016/0301-0104(95)00303-7 . [all data]

Zhuang, Zhang, et al., 2006
Zhuang, X.; Zhang, L.; Wang, J.; Ma, Y.; Yu, S.; Liu, S.; Ma, X., Study on the Photodissociation Spectra of CS, J. Phys. Chem. A, 2006, 110, 19, 6256, https://doi.org/10.1021/jp060533f . [all data]

Callomon, 1958
Callomon, J.H., Electronic Emission Spectra of the Carbon Disulphide Ion, CSFormula, Proc. Roy. Soc. (London) A244, 1958, 244, 1237, 220, https://doi.org/10.1098/rspa.1958.0038 . [all data]

Bondybey and English, 1980
Bondybey, V.E.; English, J.H., Spectroscopy and relaxation of CS2+ in solid Ne, J. Chem. Phys., 1980, 73, 7, 3098, https://doi.org/10.1063/1.440544 . [all data]

Balfour, 1976
Balfour, W.J., The and band systems of the CS, Can. J. Phys., 1976, 54, 19, 1969, https://doi.org/10.1139/p76-235 . [all data]

Venkitachalam, 1999
Venkitachalam, T.V., A tentative multiphoton ionization of CS2 molecule: Spectroscopy of Ã2«pi»u state of CS 2 + ion, Pramana, 1999, 52, 2, 177, https://doi.org/10.1007/BF02831493 . [all data]

He and Clouthier, 2006
He, S.-G.; Clouthier, D.J., The molecular structure and a Renner-Teller analysis of the ground and first excited electronic states of the jet-cooled CS[sub 2][sup +] molecular ion, J. Chem. Phys., 2006, 12, 8, 084312, https://doi.org/10.1063/1.2172612 . [all data]

Bondybey, English, et al., 1979
Bondybey, V.E.; English, J.H.; Miller, T.A., Laser induced fluorescence spectrum of matrix isolated CS+2, J. Chem. Phys., 1979, 70, 4, 1621, https://doi.org/10.1063/1.437702 . [all data]

Cheng, Lo, et al., 1995
Cheng, B.-M.; Lo, W.-J.; Hung, W.-C., Photoionization threshold of CS2 in solid neon, Chem. Phys. Lett., 1995, 236, 3, 355, https://doi.org/10.1016/0009-2614(95)00224-R . [all data]

Lorenz and Bondybey, 2000
Lorenz, M.; Bondybey, V.E., Deposition of mass-selected ions in neon matrices: CS[sub 2][sup +] and C[sub 6]F[sub 6][sup +], Low Temp. Phys., 2000, 26, 9, 778, https://doi.org/10.1063/1.1312407 . [all data]

Liu, Hochlaf, et al., 2001
Liu, J.; Hochlaf, M.; Chambaud, G.; Rosmus, P.; Ng, C.Y., High Resolution Pulsed Field Ionization-Photoelectron Bands for CS, J. Phys. Chem. A, 2001, 105, 11, 2183, https://doi.org/10.1021/jp001998n . [all data]

Zen and Lee, 1995
Zen, C.-C.; Lee, Y.-P., Laser-induced fluorescence of the A2«pi»u-X2«pi»g transition of CS2+ in solid Ne. Reanalysis of vibronic spectra, Chem. Phys. Lett., 1995, 244, 1-2, 177, https://doi.org/10.1016/0009-2614(95)00919-U . [all data]

Fischer, Lochschmidt, et al., 1993
Fischer, I.; Lochschmidt, A.; Strobel, A.; Niedner-Schatteburg, G.; Muller-Dethlefs, K.; Bondybey, V.E., The non-resonant two-photon zero kinetic energy photoelectron spectrum of CS2, Chem. Phys. Lett., 1993, 202, 542. [all data]

Huang, Cheung, et al., 1997
Huang, J.-C.; Cheung, Y.-S.; Evans, M.; Liao, C.-X.; Ng, C.Y.; Hsu, C.-W.; Heimann, P.; Lefebvre-Brion, H.; Cossart-Magos, C., A high-resolution vacuum ultraviolet photoionization, photoelectron, and pulsed field ionization study of CS2 near the CS[sub 2][sup +](X 2«PI»3/2,1/2) thresholds, J. Chem. Phys., 1997, 106, 3, 864, https://doi.org/10.1063/1.473967 . [all data]

Halasinski, Godbout, et al., 1996
Halasinski, T.M.; Godbout, J.T.; Allison, J.; Leroi, G.E., Matrix Isolation and Cold Diffusion of Mass-Selected CS, J. Phys. Chem., 1996, 100, 36, 14865, https://doi.org/10.1021/jp960862f . [all data]

Zhou and Andrews, 2000
Zhou, M.; Andrews, L., Infrared spectra of the CS[sub 2][sup -], CS[sub 2][sup +], and C[sub 2]S[sub 4][sup +] molecular ions in solid neon and argon, J. Chem. Phys., 2000, 112, 15, 6576, https://doi.org/10.1063/1.481230 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Smith, 1969
Smith, W.H., Radiative Lifetimes and Total Transition Probabilities for Some Polyatomic Species, J. Chem. Phys., 1969, 51, 8, 3410, https://doi.org/10.1063/1.1672528 . [all data]

Eland, Devoret, et al., 1976
Eland, J.H.D.; Devoret, M.; Leach, S., Quantum yields and lifetimes of molecular ion fluorescence, Chem. Phys. Lett., 1976, 43, 1, 97, https://doi.org/10.1016/0009-2614(76)80765-8 . [all data]

Maier and Thommen, 1980
Maier, J.P.; Thommen, F., Fluorescence quantum yields and cascade-free lifetimes of state selected CO+2, COS+, CS+2 and N2O+ determined by photoelectron---photon coincidence spectroscopy, Chem. Phys., 1980, 51, 3, 319, https://doi.org/10.1016/0301-0104(80)80106-6 . [all data]

Dunbar and Turner, 1981
Dunbar, R.C.; Turner, D.W., Wavelength-resolved fluorescence lifetimes of gas-phase ions: CO2+ and CS2+, Chem. Phys., 1981, 57, 3, 377, https://doi.org/10.1016/0301-0104(81)80216-9 . [all data]

Ibuki and Sugita, 1984
Ibuki, T.; Sugita, N., Lifetimes of N2O+(A), CS+2(A), and CS+2(B) states produced by pulsed EUV photons, J. Chem. Phys., 1984, 80, 10, 4625, https://doi.org/10.1063/1.446547 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References