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BF3+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 47990 ± 50 gas Haller, Koppel, et al., 1983
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003
Lucchese, Montuoro, et al., 2010


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BF stretch 810 ± 35 gas PE TPE Haller, Koppel, et al., 1983
Haller, Koppel, et al., 1983
Mackie, Shpinkova, et al., 2003
e' 3 BF stretch 2040 ± 35 gas TPE Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 35190 ± 50 gas Bassett and Lloyd, 1971
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BF stretch 760 ± 20 gas PE TPE Bassett and Lloyd, 1971
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003
a2 2 OPLA 270 ± 35 gas PE TPE Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003
e' 4 Deformation 470 ± 35 gas PE TPE Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 27460 ± 50 gas Bassett and Lloyd, 1971
Batten, Taylor, et al., 1978
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BF stretch 775 ± 20 gas PE TPE Batten, Taylor, et al., 1978
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 12370 ± 60 gas Bassett and Lloyd, 1971
Batten, Taylor, et al., 1978
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BF stretch 770 ± 60 gas PE Bassett and Lloyd, 1971
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 5890 ± 240 gas Bassett and Lloyd, 1971
Hagenow, Hottmann, et al., 1989
Shpinkova, Holland, et al., 1999
Yencha, Lopes, et al., 2002
Mackie, Shpinkova, et al., 2003

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a2 2 OPLA 509.6 Ne IR Jacox and Thompson, 1995
Jacox and Thompson, 2011
e' 3 BF3 stretch 1790.8 Ne IR Jacox and Thompson, 1995
Jacox and Thompson, 2011
4 Deformation 202 ± 24 gas TPE Yencha, Lopes, et al., 2002

Additional references: Jacox, 1994, page 201; Jacox, 1998, page 255; Jacox, 2003, page 234; Creasey, Hatherly, et al., 1993

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Haller, Koppel, et al., 1983
Haller, E.; Koppel, H.; Cederbaum, L.S.; von Niessen, W.; Bieri, G., Multimode Jahn--Teller and pseudo-Jahn--Teller effects in BF+3, J. Chem. Phys., 1983, 78, 3, 1359, https://doi.org/10.1063/1.444875 . [all data]

Yencha, Lopes, et al., 2002
Yencha, A.J.; Lopes, M.C.A.; King, G.C., Threshold photoelectron spectroscopy of boron trifluoride, Chem. Phys., 2002, 279, 1, 55, https://doi.org/10.1016/S0301-0104(02)00452-4 . [all data]

Mackie, Shpinkova, et al., 2003
Mackie, R.A.; Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A., A study of the threshold photoelectron spectra and the photoionisation yield curves of the boron trihalides, Chem. Phys., 2003, 288, 2-3, 211, https://doi.org/10.1016/S0301-0104(03)00025-9 . [all data]

Lucchese, Montuoro, et al., 2010
Lucchese, R.R.; Montuoro, R.; Kotsis, K.; Tashiro, M.; Ehara, M.; Bozek, J.D.; Das, A.; Landry, A.; Rathbone, J.; Poliakoff, E.D., The effect of vibrational motion on the dynamics of shape resonant photoionization of BF, Mol. Phys., 2010, 108, 7-9, 1055, https://doi.org/10.1080/00268971003641866 . [all data]

Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R., J. Chem. Soc. A, 1971, 641. [all data]

Hagenow, Hottmann, et al., 1989
Hagenow, G.; Hottmann, K.; Baumgartel, H., Vibronic coupling effects observed in the high-resolution He(I) photoelectron spectra of BF3, Chem. Phys. Lett., 1989, 164, 4, 395, https://doi.org/10.1016/0009-2614(89)85226-1 . [all data]

Shpinkova, Holland, et al., 1999
Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A., Mol. Phys., 1999, 96, 323. [all data]

Batten, Taylor, et al., 1978
Batten, C.F.; Taylor, J.A.; Tsai, B.P.; Meisels, G.G., Photoionization processes at threshold. II. Threshold photoelectron, photoionization, and coincidence ion-threshold photoelectron spectra of BF3, J. Chem. Phys., 1978, 69, 2547. [all data]

Jacox and Thompson, 1995
Jacox, M.E.; Thompson, W.E., Matrix isolation study of the interaction of excited neon atoms with BF3: Infrared spectra of BF2, BF+2, BF+3, and BF-3, J. Chem. Phys., 1995, 102, 12, 4747, https://doi.org/10.1063/1.469523 . [all data]

Jacox and Thompson, 2011
Jacox, M.E.; Thompson, W.E., The infrared spectra of BF3+ and BF2OH+ trapped in solid neon, J. Chem. Phys., 2011, 134, 19, 194306, https://doi.org/10.1063/1.3587133 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Creasey, Hatherly, et al., 1993
Creasey, J.C.; Hatherly, P.A.; Jones, H.M.; Lambert, I.R.; Tuckett, R.P., Vacuum UV fluorescence excitation spectroscopy of BF, Mol. Phys., 1993, 78, 4, 837, https://doi.org/10.1080/00268979300100571 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References