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Chlorine nitrate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil295.5KN/ASchack, 1967Uncertainty assigned by TRC = 3. K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Deltar85. ± 24.kJ/molIMRBWincel, Mereand, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
11.04PEWang, Li, et al., 1996 
11.56PEWang, Li, et al., 1996Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClO+12.33NO2PIJochims, Denzer, et al., 1992 
NO+13.1?PIJochims, Denzer, et al., 1992 
NO2+11.07ClOPIJochims, Denzer, et al., 1992 
NO2+13.7 ± 0.1Cl+OPIJochims, Denzer, et al., 1992 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Deltar85. ± 24.kJ/molIMRBWincel, Mereand, et al., 1997gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 25000 U gas Shamir, Yellin, et al., 1974

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO2 a-stretch 1736.9 vs gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Graham, Tuazon, et al., 1977
Ballard, Johnston, et al., 1988
Orphal, Morillon-Chapey, et al., 1997
1 NO2 a-stretch 1727.6 s Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
1 NO2 a-stretch 1734.0 s N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
1 NO2 a-stretch 1730.0 vs O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
2 NO2 s-stretch 1292.84 vs gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Graham, Tuazon, et al., 1977
Ballard, Johnston, et al., 1988
Orphal, Morillon-Chapey, et al., 1994
Orphal, Morillon-Chapey, et al., 1997
Domenech, Flaud, et al., 1997
2 NO2 s-stretch 1285.8 vs Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
2 NO2 s-stretch 1291.4 vs N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
2 NO2 s-stretch 1289.7 s O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
3 ClO stretch 809.4 s gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Graham, Tuazon, et al., 1977
Ballard, Johnston, et al., 1988
Orphal, Morillon-Chapey, et al., 1997
3 ClO stretch 801.6 m Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
3 ClO stretch 809.7 w m N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
3 ClO stretch 808.1 m O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
4 Mixed 780.22 m s gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Graham, Tuazon, et al., 1977
Ballard, Johnston, et al., 1988
Chiang and Lee, 1991
4 Mixed 780.22 m s gas DL Bell, Duxbury, et al., 1992
Xu, Blake, et al., 1996
McPheat and Duxbury, 1996
Orphal, Morillon-Chapey, et al., 1997
4 Mixed 775.6 m Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
4 Mixed 778.6 m N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
4 Mixed 776.3 m O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
5 Mixed 563.1 s gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Orphal, Morillon-Chapey, et al., 1997
5 Mixed 560.9 m s Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
5 Mixed 563.2 w m N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
5 Mixed 559.0 m O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
6 NO2 rock 434.0 m gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Orphal, Morillon-Chapey, et al., 1997
6 NO2 rock 426 Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
6 NO2 rock 436.5 w N2 IR Griffith, Tyndall, et al., 1984
6 NO2 rock 435.0 O2 IR Tevault and Smardzewski, 1978
7 ClO rock 273.3 w gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Orphal, Morillon-Chapey, et al., 1997
a 8 NO2 wag 711.21 w gas IR Miller, Bernitt, et al., 1967
Orphal, Morillon-Chapey, et al., 1997
Flaud, Lafferty, et al., 2003
8 NO2 wag 710.8 w Ar IR Bhatia, George-Taylor, et al., 1983
Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
8 NO2 wag 708.4 w N2 IR Griffith, Tyndall, et al., 1984
De Saxce and Schriver, 1992
8 NO2 wag 704.6 w m O2 IR Tevault and Smardzewski, 1978
De Saxce and Schriver, 1992
9 Torsion 123.72 gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Fleming, 1977
Chance and Traub, 1982
Orphal, Morillon-Chapey, et al., 1997
Flaud, Lafferty, et al., 2003

Additional references: Jacox, 1994, page 288; Jacox, 1998, page 302; Jacox, 2003, page 301; Illies and Takacs, 1976; Suenram and Johnson, 1977; Suenram and Lovas, 1984; Davidson, Cantrell, et al., 1987; Casper, Lambotte, et al., 1993; Muller, Helminger, et al., 1997

Notes

wWeak
mMedium
sStrong
vsVery strong
UUpper bound
dPhotodissociation threshold

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schack, 1967
Schack, C.J., New Synthesis of Chlorine Nitrate, Inorg. Chem., 1967, 6, 1938-9. [all data]

Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W., Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-, J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146 . [all data]

Wang, Li, et al., 1996
Wang, D.; Li, Y.; Jiang, P.; Wang, X.; Chen, B., The study of HeI photoelectron spectroscopy (PES) of the electronic structure for ClONO2, Chem. Phys. Lett., 1996, 260, 99. [all data]

Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H., Photochemical decay reactions of N2O5, HNO3, ClNO3 and BrNO3 in the energy range 10-20 eV, Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]

Shamir, Yellin, et al., 1974
Shamir, J.; Yellin, D.; Claassen, H.H., Isr. J. Chem., 1974, 12, 1015. [all data]

Miller, Bernitt, et al., 1967
Miller, R.H.; Bernitt, D.L.; Hisatsune, I.C., Spectrochim. Acta, 1967, 23A, 223. [all data]

Graham, Tuazon, et al., 1977
Graham, R.A.; Tuazon, E.C.; Winer, A.M.; Pitts, J.N., Jr.; Molina, L.T.; Beaman, L.; Molina, M.J., High resolution infrared absorptivities for gaseous chlorine nitrate, Geophys. Res. Lett., 1977, 4, 1, 3, https://doi.org/10.1029/GL004i001p00003 . [all data]

Ballard, Johnston, et al., 1988
Ballard, J.; Johnston, W.B.; Gunson, M.R.; Wassell, P.T., Absolute absorption coefficients of ClONO, J. Geophys. Res., 1988, 93(D), D2, 1659, https://doi.org/10.1029/JD093iD02p01659 . [all data]

Orphal, Morillon-Chapey, et al., 1997
Orphal, J.; Morillon-Chapey, M.; Diallo, A.; Guelachvili, G., High-Resolution Infrared Spectra and Harmonic Force Field of Chlorine Nitrate, J. Phys. Chem. A, 1997, 101, 6, 10062, https://doi.org/10.1021/jp9619595 . [all data]

Bhatia, George-Taylor, et al., 1983
Bhatia, S.C.; George-Taylor, M.; Merideth, C.W.; Hall, J.H., Jr., Low-temperature infrared spectrum of chlorine nitrate and evidence for the existence of chlorine nitrate (ClOONO), J. Phys. Chem., 1983, 87, 7, 1091, https://doi.org/10.1021/j100230a001 . [all data]

Griffith, Tyndall, et al., 1984
Griffith, D.W.T.; Tyndall, G.S.; Burrows, J.P.; Moortgat, G.K., Matrix-isolation spectra of chlorine nitrate, Chem. Phys. Lett., 1984, 107, 3, 341, https://doi.org/10.1016/0009-2614(84)85141-6 . [all data]

De Saxce and Schriver, 1992
De Saxce, A.; Schriver, L., An infrared study of the UV photolysis of chlorine nitrate trapped in various matrices at 11 K, Chem. Phys. Lett., 1992, 199, 6, 596, https://doi.org/10.1016/0009-2614(92)85016-4 . [all data]

Tevault and Smardzewski, 1978
Tevault, D.E.; Smardzewski, R.R., Synthesis of chlorine nitrate by photolysis of nitrosyl chloride in solid oxygen at 10 K, J. Phys. Chem., 1978, 82, 4, 375, https://doi.org/10.1021/j100493a001 . [all data]

Orphal, Morillon-Chapey, et al., 1994
Orphal, J.; Morillon-Chapey, M.; Guelachvili, G., High-resolution absorption cross sections of chlorine nitrate in the «nu», J. Geophys. Res., 1994, 99(D), D7, 14549, https://doi.org/10.1029/94JD00671 . [all data]

Domenech, Flaud, et al., 1997
Domenech, J.L.; Flaud, J.-M.; Fraser, G.T.; Andrews, A.M.; Lafferty, W.J.; Watson, P.L., Infrared Diode-Laser Molecular-Beam Spectrum of the «nu»2Band of Chlorine Nitrate at 1293 cm-1, J. Mol. Spectrosc., 1997, 183, 2, 228, https://doi.org/10.1006/jmsp.1997.7260 . [all data]

Chiang and Lee, 1991
Chiang, S.-Y.; Lee, Y.-P., Vibronic analysis of the A 2A1--X 2E laser-induced fluorescence of jet-cooled CH3S, J. Chem. Phys., 1991, 95, 1, 66, https://doi.org/10.1063/1.461786 . [all data]

Bell, Duxbury, et al., 1992
Bell, W.; Duxbury, G.; Stuart, D.D., High-resolution spectra of the «nu»4 band of chlorine nitrate, J. Mol. Spectrosc., 1992, 152, 2, 285, https://doi.org/10.1016/0022-2852(92)90069-Z . [all data]

Xu, Blake, et al., 1996
Xu, S.; Blake, T.A.; Sharpe, S.W., High-Resolution Infrared Spectroscopy of the «nu»4Fundamental Band of Chlorine Nitrate, J. Mol. Spectrosc., 1996, 175, 2, 303, https://doi.org/10.1006/jmsp.1996.0036 . [all data]

McPheat and Duxbury, 1996
McPheat, R.; Duxbury, G., Absorption coefficients of ClONO, J. Geophys. Res., 1996, 101(D), D3, 6803, https://doi.org/10.1029/95JD02927 . [all data]

Flaud, Lafferty, et al., 2003
Flaud, J.-M.; Lafferty, W.J.; Orphal, J.; Birk, M.; Wagner, G., First high-resolution analyses of the «nu», Mol. Phys., 2003, 101, 10, 1527, https://doi.org/10.1080/0026897031000108087 . [all data]

Fleming, 1977
Fleming, J.W., Far infrared rotational and torsional absorption spectra of chlorine nitrate, Chem. Phys. Lett., 1977, 50, 1, 107, https://doi.org/10.1016/0009-2614(77)80690-8 . [all data]

Chance and Traub, 1982
Chance, K.V.; Traub, W.A., The torsional spectrum of chlorine nitrate, J. Mol. Spectrosc., 1982, 95, 2, 306, https://doi.org/10.1016/0022-2852(82)90131-X . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Illies and Takacs, 1976
Illies, A.J.; Takacs, G.A., Gas phase ultra-violet photoabsorption cross-sections for nitrosyl chloride and nitryl chloride, J. Photochem., 1976, 6, 1, 35, https://doi.org/10.1016/0047-2670(76)87005-0 . [all data]

Suenram and Johnson, 1977
Suenram, R.D.; Johnson, D.R., Microwave spectrum of chlorine nitrate (ClNO3), J. Mol. Spectrosc., 1977, 65, 2, 239, https://doi.org/10.1016/0022-2852(77)90191-6 . [all data]

Suenram and Lovas, 1984
Suenram, R.D.; Lovas, F.J., Millimeter wave spectrum of chlorine nitrate, J. Mol. Spectrosc., 1984, 105, 2, 351, https://doi.org/10.1016/0022-2852(84)90225-X . [all data]

Davidson, Cantrell, et al., 1987
Davidson, J.A.; Cantrell, C.A.; Shetter, R.E.; McDaniel, A.H.; Calvert, J.G., Absolute infrared absorption cross sections for ClONO, J. Geophys. Res., 1987, 92(D), D9, 10921, https://doi.org/10.1029/JD092iD09p10921 . [all data]

Casper, Lambotte, et al., 1993
Casper, B.; Lambotte, P.; Minkwitz, R.; Oberhammer, H., Gas-phase structures of chlorine and bromine nitrate (ClONO2 and BrONO2), J. Phys. Chem., 1993, 97, 39, 9992, https://doi.org/10.1021/j100141a017 . [all data]

Muller, Helminger, et al., 1997
Muller, H.S.P.; Helminger, P.; Young, S.H., Millimeter and Submillimeter Spectroscopy of Chlorine Nitrate: The Cl Quadrupole Tensor and the Harmonic Force Field, J. Mol. Spectrosc., 1997, 181, 2, 363, https://doi.org/10.1006/jmsp.1996.7183 . [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Vibrational and/or electronic energy levels, NIST Free Links, References