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dimethyloxosilane


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H5OSi- + Hydrogen cation = dimethyloxosilane

By formula: C2H5OSi- + H+ = C2H6OSi

Quantity Value Units Method Reference Comment
Deltar1521. ± 17.kJ/molG+TSDamrauer and Krempp, 1990gas phase; between CF3CH2OH and CH3CHO in acidity
Deltar1522. ± 17.kJ/molG+TSFroelicher, Freiser, et al., 1984gas phase; Between aniline, CF3CH2OH in acidity
Quantity Value Units Method Reference Comment
Deltar1492. ± 17.kJ/molIMRBDamrauer and Krempp, 1990gas phase; between CF3CH2OH and CH3CHO in acidity
Deltar1492. ± 17.kJ/molIMRBFroelicher, Freiser, et al., 1984gas phase; Between aniline, CF3CH2OH in acidity

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer and Krempp, 1990
Damrauer, R.; Krempp, M., Gas Phase Ion-Molecule Chemistry of Methoxy-Substituted Silanes: Collision Induced Decomposition of Siloxide Ions Leading to Anions of Silaacetaldehyde and Methyl Silaformate, Organomet., 1990, 9, 4, 999, https://doi.org/10.1021/om00118a015 . [all data]

Froelicher, Freiser, et al., 1984
Froelicher, S.W.; Freiser, B.S.; Squires, R.R., Dimethylsilanone Enolate, J. Am. Chem. Soc., 1984, 106, 22, 6863, https://doi.org/10.1021/ja00334a077 . [all data]


Notes

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