- Formula: C2H6OSi
- Molecular weight: 74.1539
- IUPAC Standard InChI:
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- IUPAC Standard InChIKey: SEUDSDUUJXTXSV-UHFFFAOYSA-N
- CAS Registry Number: 47956-45-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
- Other names: Silane, dimethyloxo-
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Reaction thermochemistry data
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Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
C2H5OSi- + =
By formula: C2H5OSi- + H+ = C2H6OSi
|rH°||1521. ± 17.||kJ/mol||G+TS||Damrauer and Krempp, 1990||gas phase; between CF3CH2OH and CH3CHO in acidity|
|rH°||1522. ± 17.||kJ/mol||G+TS||Froelicher, Freiser, et al., 1984||gas phase; Between aniline, CF3CH2OH in acidity|
|rG°||1492. ± 17.||kJ/mol||IMRB||Damrauer and Krempp, 1990||gas phase; between CF3CH2OH and CH3CHO in acidity|
|rG°||1492. ± 17.||kJ/mol||IMRB||Froelicher, Freiser, et al., 1984||gas phase; Between aniline, CF3CH2OH in acidity|
Go To: Top, Reaction thermochemistry data, Notes
Damrauer and Krempp, 1990
Damrauer, R.; Krempp, M., Gas Phase Ion-Molecule Chemistry of Methoxy-Substituted Silanes: Collision Induced Decomposition of Siloxide Ions Leading to Anions of Silaacetaldehyde and Methyl Silaformate, Organomet., 1990, 9, 4, 999, https://doi.org/10.1021/om00118a015 . [all data]
Froelicher, Freiser, et al., 1984
Froelicher, S.W.; Freiser, B.S.; Squires, R.R., Dimethylsilanone Enolate, J. Am. Chem. Soc., 1984, 106, 22, 6863, https://doi.org/10.1021/ja00334a077 . [all data]
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
rG° Free energy of reaction at standard conditions rH° Enthalpy of reaction at standard conditions
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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