Perfluorobicyclo-[4.4.0]-dec-1,6-ene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-765.7 ± 1.1kcal/molCcrZhogina, Papina, et al., 1988Uc=-3560.0±4.6 kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-776.5 ± 1.1kcal/molCcrZhogina, Papina, et al., 1988Uc=-3560.0±4.6 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-848.5 ± 1.1kcal/molCcrZhogina, Papina, et al., 1988Uc=-3560.0±4.6 kJ/mol; ALS
Quantity Value Units Method Reference Comment
liquid117.4cal/mol*KN/AZhogin, Kosarukina, et al., 1981DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
102.4298.15Zhogin, Kosarukina, et al., 1981T = 6 to 300 K. 0.41 mole % impurity of sample; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple264.09KN/AZhogin, Kosarukina, et al., 1981Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δvap10.8 ± 0.02kcal/molCVarushchenko, Druzhinina, et al., 1996AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.502263.Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.190200.0crystaline, IIIcrystaline, IIZhogin, Kosarukina, et al., 1981DH
0.2660233.4crystaline, IIcrystaline, IZhogin, Kosarukina, et al., 1981DH
2.5031264.09crystaline, IliquidZhogin, Kosarukina, et al., 1981DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.901200.0crystaline, IIIcrystaline, IIZhogin, Kosarukina, et al., 1981DH
1.14233.4crystaline, IIcrystaline, IZhogin, Kosarukina, et al., 1981DH
9.479264.09crystaline, IliquidZhogin, Kosarukina, et al., 1981DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhogina, Papina, et al., 1988
Zhogina, E.V.; Papina, T.S.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A., Standard enthalpy of formation of perfluorobicyclo-[4,4,0]-dec-1,6-ene, Russ. J. Phys. Chem. (Engl. Transl.), 1988, 62, 569-570. [all data]

Zhogin, Kosarukina, et al., 1981
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A., The heat capacity in the temperature range 6-300 K, phase transformations, and thermodynamic functions of perfluorobicyclo(4,4,0)dec-1,6-ene, Zhur. Fiz. Khim., 1981, 55, 98-103. [all data]

Varushchenko, Druzhinina, et al., 1996
Varushchenko, Raisa M.; Druzhinina, Anna I.; Pashchenko, Larisa L., Thermodynamics of vaporization of some cyclic perfluorocarbons, Fluid Phase Equilibria, 1996, 126, 1, 93-104, https://doi.org/10.1016/S0378-3812(96)03111-1 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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