Ethynyl radical

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C2H2- • 4294967295Ethynyl radical) + Ethynyl radical = C2H2-

By formula: (C2H2- • 4294967295C2H) + C2H = C2H2-

Quantity Value Units Method Reference Comment
Δr328. ± 15.kJ/molN/AErvin, Gronert, et al., 1990gas phase; Vinylidene neutral: ΔHf<=99±2 kcal, Kiefer, Sidhu, et al., 1989
Δr187. ± 14.kJ/molTherGuo and Grabowski, 1990gas phase; Between PhF, Me3P

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C., Bonds Strengths of Ethylene and Acetylene, J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013 . [all data]

Kiefer, Sidhu, et al., 1989
Kiefer, J.H.; Sidhu, S.S.; Kumaran, S.S.; Irdan, E.A., RRKM Model of C2H4 Dissociation: Heat of Formation of Vinylidene, Chem. Phys. Lett., 1989, 159, 1, 32, https://doi.org/10.1016/S0009-2614(89)87448-2 . [all data]

Guo and Grabowski, 1990
Guo, Y.; Grabowski, J.J., Gas Phase Ion Chemistry of the Vinylidene Radical Anion and the Acidity of the Vinyl Radical, Int. J. Mass Spectrom. Ion Proc., 1990, 97, 3, 253, https://doi.org/10.1016/0168-1176(90)85003-K . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References