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platinum hexafluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
7.00 ± 0.35TDEqKorobov, Kuznetsov, et al., 19892PtF4 + 2AlF4- <=> 2AlF3 + PtF4- + PtF6-, «DELTA»H = 29.4±1.0 kcal/mol.; value altered from reference due to conversion from electron convention to ion convention
8.00 ± 0.30TDEqNikitin, Sidorov, et al., 1981EA: 2.8 eV > PtF4; value altered from reference due to conversion from electron convention to ion convention
>5.14 ± 0.50NBIECompton, Reinhardt, et al., 1978 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Korobov, Kuznetsov, et al., 1989
Korobov, M.V.; Kuznetsov, S.V.; Sidorov, L.N.; Shipachev, V.A.; Mit'kin, V.N., Gas Phase Negative Ions of Platinum Metal Fluorides. II. Electron Affinity of Platinum Metal Hexafluorides, Int. J. Mass Spectrom. Ion Proc., 1989, 87, 1, 13, https://doi.org/10.1016/0168-1176(89)80002-3 . [all data]

Nikitin, Sidorov, et al., 1981
Nikitin, M.I.; Sidorov, L.N.; Korobov, M.V., The electron affinity of platinum hexafluoride, Int. J. Mass Spectrom. Ion Processes, 1981, 37, 13. [all data]

Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D., Collisional ionization between fast alkali atoms and selected hexafluoride molecules, J. Chem. Phys., 1978, 68, 2023. [all data]


Notes

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