Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Oxacyclotetradecan-2-one

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple300.42KN/ALebedev, Evstropov, et al., 1981Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Ttriple300.4KN/ALebedev, Evstropov, et al., 1981, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap75.0kJ/molN/AWiberg and Waldron, 1991DRB
Deltavap72.9 ± 1.7kJ/molMMWiberg and Waldron, 1991Based on data from 375. - 405. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
66.6 ± 1.1390.MMWiberg and Waldron, 1991Based on data from 375. - 405. K.; AC
67.5408.AStephenson and Malanowski, 1987Based on data from 393. - 443. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.08300.4Domalski and Hearing, 1996AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
18.150290.63crystaline, IIcrystaline, ILebedev, Evstropov, et al., 1981, 3DH
9.060300.4crystaline, IliquidLebedev, Evstropov, et al., 1981, 3DH
18.150290.63crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1981DH
9.058300.4crystaline, IliquidLebedev, Yevstropov, et al., 1981DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
62.45290.63crystaline, IIcrystaline, ILebedev, Evstropov, et al., 1981, 3DH
30.2300.4crystaline, IliquidLebedev, Evstropov, et al., 1981, 3DH
62.3290.63crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1981DH
30.2300.4crystaline, IliquidLebedev, Yevstropov, et al., 1981DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Evstropov, et al., 1981
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, Ye.G., Thermodynamics of undecanolactone, tridecanolactone, and pentadecanolactone from 0 to 340 K, J. Chem. Thermodyn., 1981, 13, 1185. [all data]

Lebedev, Evstropov, et al., 1981, 2
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, E.G.; Sheveleva, N.P., Thermodynamics of Tridecanolactone, Its Polymerization Process, and the Resultant Poly(tridecanolactone) in the 0 - 430 K Range, Vysokomol. Soedin, Ser. B, 1981, 24, 551-4. [all data]

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Lebedev, Evstropov, et al., 1981, 3
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, Y.G.; Sheveleva, N.P., Thermodynamics of tridecanolactone, its polymerization process, and the resultant poly(tridecanolactone) in the 0-430 K range, Vysokomol. Soedin., 1981, B23, 551-554. [all data]

Lebedev, Yevstropov, et al., 1981
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Y.G., Thermodynamic properties of undecanolactone over the range, 1981, Termodin. [all data]


Notes

Go To: Top, Phase change data, References