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Naphthalene, 2-bromo-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil554.7KN/AWeast and Grasselli, 1989BS
Tboil554.15KN/ACooper, Crowne, et al., 1967Uncertainty assigned by TRC = 0.7 K; TRC
Quantity Value Units Method Reference Comment
Tfus332.KN/AKhanna, Khetarpal, et al., 1981Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Deltavap66.1 ± 0.4kJ/molGSVerevkin, 2003Based on data from 330. - 360. K.; AC
Quantity Value Units Method Reference Comment
Deltasub81.2 ± 1.0kJ/molCRibeiro da Silva, Ferrao, et al., 1993ALS
Deltasub81.2 ± 1.0kJ/molCda Silva, 1993AC
Deltasub64. ± 5.kJ/molTE,MEFerro, Piacente, et al., 1981Based on data from 275. - 378. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
42.5354.N/ADykyj, Svoboda, et al., 1999Based on data from 330. - 378. K.; AC
40.4340.ME,TEFerro, Piacente, et al., 1981Based on data from 322. - 359. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
14.4329.Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
18.09319.Domalski and Hearing, 1996CAL
43.76329.

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
5.770319.crystaline, IIIcrystaline, IChanh, Haget, et al., 1981DH
14.400329.crystaline, IliquidChanh, Haget, et al., 1981A second order transition occurs between crystalline phases c,I and c,II over the temperature range 275 to 319 K.; DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
18.09319.crystaline, IIIcrystaline, IChanh, Haget, et al., 1981DH
43.77329.crystaline, IliquidChanh, Haget, et al., 1981A; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Cooper, Crowne, et al., 1967
Cooper, A.R.; Crowne, C.W.P.; Farrell, P.G., Gas-Liquid Chromatographic Studies of Electron-Donor-Acceptor Systems, Trans. Faraday Soc., 1967, 63, 447. [all data]

Khanna, Khetarpal, et al., 1981
Khanna, M.S.; Khetarpal, S.C.; Lal, K.; Bhatnagar, H.L., Thermodynamic studies on melting of some alpha- and beta-halogen derivatives of napthalene, Indian J. Chem> Sect. A, 1981, 20, 544. [all data]

Verevkin, 2003
Verevkin, Sergey P., Vapor pressures and enthalpies of vaporization of a series of 1- and 2-halogenated naphthalenes, The Journal of Chemical Thermodynamics, 2003, 35, 8, 1237-1251, https://doi.org/10.1016/S0021-9614(03)00051-X . [all data]

Ribeiro da Silva, Ferrao, et al., 1993
Ribeiro da Silva, M.A.V.; Ferrao, M.L.C.C.H.; Lopes, A.J.M., Enthalpies of combustion of each of the two bromonaphthalenes, J. Chem. Thermodyn., 1993, 25, 229-235. [all data]

da Silva, 1993
da Silva, M., Enthalpies of combustion of each of the two bromonaphthalenes, Z. Chem., 1993, 25, 2, 229-235, https://doi.org/10.1006/jcht.1993.1022 . [all data]

Ferro, Piacente, et al., 1981
Ferro, D.; Piacente, V.; Pelino, M., Rev. Roum. Chim., 1981, 26, 9. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Chanh, Haget, et al., 1981
Chanh, N.B.; Haget, Y.; Meresse, A.; Louer, D.; Shirley, R., Destructive and nondestructive phase transitions of the molecular crystal 2-bromonaphthalene, J. Phys. Chem. Solids, 1981, 42, 217-225. [all data]


Notes

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