HSO

Vibrational and/or electronic energy levels

Go To: Top, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14367 gas A-X 520 960 Schurath, Weber, et al., 1977
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SO stretch 702 ± 5 gas CL Schurath, Weber, et al., 1977

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SH stretch 2325 ± 3 gas LF Yoshikawa, Watanabe, et al., 2009
2 Bend 1079 ± 3 gas CL LF Schurath, Weber, et al., 1977
Yoshikawa, Watanabe, et al., 2009
3 SO stretch 1009.36 gas LMR LF Sears and McKellar, 1983
Yoshikawa, Watanabe, et al., 2009

Additional references: Jacox, 1994, page 50; Jacox, 1998, page 154; Kakimoto, Saito, et al., 1980; Ohashi, Kakimoto, et al., 1980; Endo, Saito, et al., 1981; Kawasaki, Kasatani, et al., 1983; Ohashi, Saito, et al., 1988; Takehisa and Ohashi, 1988; Hung and Lee, 1993

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schurath, Weber, et al., 1977
Schurath, U.; Weber, M.; Becker, K.H., Electronic spectrum and structure of the HSO radical, J. Chem. Phys., 1977, 67, 1, 110, https://doi.org/10.1063/1.434553 . [all data]

Yoshikawa, Watanabe, et al., 2009
Yoshikawa, T.; Watanabe, A.; Sumiyoshi, Y.; Endo, Y., Laser spectroscopy of the 2A´-2A´´ system for the HSO radical, J. Mol. Spectrosc., 2009, 254, 2, 119, https://doi.org/10.1016/j.jms.2009.01.018 . [all data]

Sears and McKellar, 1983
Sears, T.J.; McKellar, A.R.W., The laser magnetic resonance spectrum of the, Mol. Phys., 1983, 49, 1, 25, https://doi.org/10.1080/00268978300101011 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kakimoto, Saito, et al., 1980
Kakimoto, M.; Saito, S.; Hirota, E., Doppler-limited dye laser excitation spectroscopy of the HSO radical, J. Mol. Spectrosc., 1980, 80, 2, 334, https://doi.org/10.1016/0022-2852(80)90145-9 . [all data]

Ohashi, Kakimoto, et al., 1980
Ohashi, N.; Kakimoto, M.; Saito, S.; Hirota, E., Doppler-limited dye laser excitation spectroscopy of the DSO radical, J. Mol. Spectrosc., 1980, 84, 1, 204, https://doi.org/10.1016/0022-2852(80)90254-4 . [all data]

Endo, Saito, et al., 1981
Endo, Y.; Saito, S.; Hirota, E., Microwave spectra of the HSO and DSO radicals, J. Chem. Phys., 1981, 75, 9, 4379, https://doi.org/10.1063/1.442600 . [all data]

Kawasaki, Kasatani, et al., 1983
Kawasaki, M.; Kasatani, K.; Tanahashi, S.; Sato, H.; Fujimura, Y., Fluorescence lifetimes of single vibrational levels in HSO (A 2A´), J. Chem. Phys., 1983, 78, 12, 7146, https://doi.org/10.1063/1.444754 . [all data]

Ohashi, Saito, et al., 1988
Ohashi, N.; Saito, S.; Suzuki, T.; Hirota, E., Dye laser excitation spectroscopy of two new bands of the DSO radical in 6100-Å region, J. Mol. Spectrosc., 1988, 127, 2, 481, https://doi.org/10.1016/0022-2852(88)90136-1 . [all data]

Takehisa and Ohashi, 1988
Takehisa, Y.; Ohashi, N., Dye laser excitation spectroscopy of the DSO radical in the A2A´(022) ← X2A´´(000) band, J. Mol. Spectrosc., 1988, 130, 1, 221, https://doi.org/10.1016/0022-2852(88)90295-0 . [all data]

Hung and Lee, 1993
Hung, W.C.; Lee, Y.P., J. Chin. Chem. Soc. (Taipei), 1993, 40, 407. [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, NIST Free Links, References