Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

SF4+


Reaction thermochemistry data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

By formula: (F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar59.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

F4S+ + F6S- = (F4S+ bullet F6S-)

By formula: F4S+ + F6S- = (F4S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 51600 ± 800 gas Cowley, Lattman, et al., 1979
Costa, Lloyd, et al., 1981
Jochims, Ruhl, et al., 1989

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 46800 ± 400 gas Cowley, Lattman, et al., 1979
Costa, Lloyd, et al., 1981
Jochims, Ruhl, et al., 1989

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 43000 ± 400 gas Cowley, Lattman, et al., 1979
Costa, Lloyd, et al., 1981
Jochims, Ruhl, et al., 1989

State:   C,D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 31460 ± 400 gas Cowley, Lattman, et al., 1979
Costa, Lloyd, et al., 1981
Jochims, Ruhl, et al., 1989

State:   A,B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 25580 ± 400 gas Cowley, Lattman, et al., 1979
Costa, Lloyd, et al., 1981
Jochims, Ruhl, et al., 1989

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

b1 6 SF stretch 975.4 Ne IR Lugez, Jacox, et al., 1998
b2 8 SF stretch 698.3 Ne IR Lugez, Jacox, et al., 1998

Additional references: Jacox, 1998, page 307; Jacox, 2003, page 307

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Cowley, Lattman, et al., 1979
Cowley, A.H.; Lattman, M.; Walker, M.L., A photoelectron spectroscopic-molecular orbital study of sulfur tetrafluoride and related fluorosulfuranes, J. Am. Chem. Soc., 1979, 101, 15, 4074, https://doi.org/10.1021/ja00509a011 . [all data]

Costa, Lloyd, et al., 1981
Costa, N.C.V.; Lloyd, D.R.; Roberts, P.J.; Cruickshank, D.W.J.; Avramides, E.; Chablo, A.; Collins, G.A.D., et al., J. Chem. Soc., 1981, Faraday Trans. 2 77, 899. [all data]

Jochims, Ruhl, et al., 1989
Jochims, H.-W.; Ruhl, E.; Baumgartel, H., Z. Naturforsch., 1989, 44b, 13. [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References