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sym-C6F3Br3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 13510 ± 10 gas B-X 725 830 Maier, Marthaler, et al., 1980
To = 13255 Ne B-X 600 870 Bondybey, Sears, et al., 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 2 1073 T Ne AB LF Bondybey, Sears, et al., 1981
3 578 Ne AB LF Bondybey, Sears, et al., 1981
e' 8 1555 Ne AB LF Bondybey, Sears, et al., 1981
9 1398 T Ne AB LF Bondybey, Sears, et al., 1981
10 1045 Ne AB LF Bondybey, Sears, et al., 1981
11 685 T Ne AB LF Bondybey, Sears, et al., 1981
12 381 Ne AB LF Bondybey, Sears, et al., 1981
13 253 Ne AB LF Bondybey, Sears, et al., 1981

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 3 583 Ne LF Bondybey, Sears, et al., 1981
e' 8 1727 Ne LF Bondybey, Sears, et al., 1981
10 1147 Ne LF Bondybey, Sears, et al., 1981
12 387 Ne LF Bondybey, Sears, et al., 1981
13 292 Ne LF Bondybey, Sears, et al., 1981

Additional references: Jacox, 1994, page 439

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M.; Shiley, R.H., Emission spectra of the cations of 1,3- and 1,4-dibromotetrafluorobenzene and of 1,3,5-tribromotrifluorobenzene in the gaseous phase, Chem. Phys., 1980, 47, 3, 307, https://doi.org/10.1016/0301-0104(80)85016-6 . [all data]

Bondybey, Sears, et al., 1981
Bondybey, V.E.; Sears, T.J.; Miller, T.A.; Vaughn, C.; English, J.H.; Shiley, R.S., Ne matrix spectra of the sym-C6Br3F3+ radical cation, Chem. Phys., 1981, 61, 1-2, 9, https://doi.org/10.1016/0301-0104(81)85043-4 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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