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Silabenzene


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.8PEBock, Rosmus, et al., 1984LBLHLM
8.0PEBock, Rosmus, et al., 1984Vertical value; LBLHLM
8.0PESolouki, Rosmus, et al., 1980Vertical value; LLK

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

SiH stretch 2244 s Ar IR Maier, Mihm, et al., 1984
2217 s Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
1526 m Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
1502 s Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
1409 w m Ar IR Maier, Mihm, et al., 1984
1354 vs Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
1259 vs Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
1069 w m Ar IR Maier, Mihm, et al., 1984
886 m Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
720 w m Ar IR Maier, Mihm, et al., 1984
716 Ar IR Maier, Mihm, et al., 1984
700 vs Ar IR Maier, Mihm, et al., 1984
698 Ar IR Maier, Mihm, et al., 1984
568 vs Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
565 Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984
419 s Ar IR Maier, Mihm, et al., 1980
Maier, Mihm, et al., 1984

Additional references: Jacox, 1994, page 404

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bock, Rosmus, et al., 1984
Bock, H.; Rosmus, P.; Solouki, B.; Maier, G., Gas phase reactions. XXXXVI. Silabenzene: Photoelectron spectrum from 1-sila-2,5-hexadiene pyrolysis and assignment of valence ionisation energies, J. Organomet. Chem., 1984, 271, 145. [all data]

Solouki, Rosmus, et al., 1980
Solouki, B.; Rosmus, P.; Bock, H.; Maier, G., Short-path pyrolysis: Silabenzene, Angew. Chem. Int. Ed. Engl., 1980, 19, 51. [all data]

Maier, Mihm, et al., 1984
Maier, G.; Mihm, G.; Baumgartner, R.O.W.; Reisenauer, H.P., Hetero-«pi»-Systeme, 7. Silabenzol, Chem. Ber., 1984, 117, 7, 2337, https://doi.org/10.1002/cber.19841170707 . [all data]

Maier, Mihm, et al., 1980
Maier, G.; Mihm, G.; Reisenauer, H.P., Silabenzol, Angew. Chem., 1980, 92, 1, 58, https://doi.org/10.1002/ange.19800920120 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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