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Borane, chlorothioxo-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
10.5 ± 0.1PEKirby, Kroto, et al., 1978

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BS stretch 1407.56 gas IR August, Aziz, et al., 1988
Chau, Tang, et al., 1994
McNaughton and Tay-Lim, 2000
Pi 2 Bend 300 ± 40 gas MW Kirby and Kroto, 1980
Sigma+ 3 BCl stretch 529.90 gas IR August, Aziz, et al., 1988
Chau, Tang, et al., 1994
McNaughton and Tay-Lim, 2000

Additional references: Jacox, 1994, page 85; Jacox, 1998, page 189; Jacox, 2003, page 130; Kirby, Kroto, et al., 1978; Bizzocchi, Degli Esposti, et al., 2002


References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kirby, Kroto, et al., 1978
Kirby, C.; Kroto, H.W.; Westwood, N.P.C., Detection of chlorothioborine, ClB=S, a new unstable triatomic molecule, by photoelectron microwave spectroscopy, J. Am. Chem. Soc., 1978, 100, 3766. [all data]

August, Aziz, et al., 1988
August, J.A.; Aziz, S.; Kroto, H.W.; Suffolk, R.J., unpublished data, 1988. [all data]

Chau, Tang, et al., 1994
Chau, F.T.; Tang, Y.W.; Song, X., Geometries of thioborine and chlorothioboron cations, J. Electron Spectrosc. Relat. Phenom., 1994, 70, 1, 39, https://doi.org/10.1016/0368-2048(94)02209-I . [all data]

McNaughton and Tay-Lim, 2000
McNaughton, D.; Tay-Lim, R., The High-Resolution FTIR Spectrum and Equilibrium Structure of Chloro(sulphido)boron, J. Mol. Spectrosc., 2000, 202, 1, 89, https://doi.org/10.1006/jmsp.2000.8103 . [all data]

Kirby and Kroto, 1980
Kirby, C.; Kroto, H.W., The microwave spectrum of the transient molecule chloro(sulphido)boron, ClB«58875»S: Substitution structure, dipole moment, quadrupole moment, and vibration-rotation analysis, J. Mol. Spectrosc., 1980, 83, 1, 130, https://doi.org/10.1016/0022-2852(80)90316-1 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Bizzocchi, Degli Esposti, et al., 2002
Bizzocchi, L.; Degli Esposti, C.; Puzarini, C., Millimeter-Wave Spectroscopy of ClBS: An Improved Evaluation of the Equilibrium Structure of Chlorothioborine, J. Mol. Spectrosc., 2002, 216, 2, 177, https://doi.org/10.1006/jmsp.2002.8538 . [all data]


Notes

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