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Bullvalene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid262.3 ± 3.3kJ/molCcbMansson and Sunner, 1981ALS
Quantity Value Units Method Reference Comment
Deltacsolid-5626.5 ± 3.0kJ/molCcbMansson and Sunner, 1981Corresponding «DELTA»fsolid = 262.28 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar174.66J/mol*KN/AFalk B., 1980DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
190.38298.15Falk B., 1980T = 5 to 450 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mansson and Sunner, 1981
Mansson, M.; Sunner, S., Enthalpy of formation and strain energy of bullvalene (tricyclo[3.3.2.04,6]deca-2,7,9-triene); a calorimetric study, J. Chem. Thermodyn., 1981, 13, 671-675. [all data]

Falk B., 1980
Falk B., Heat capacity and thermodynamic properties of tricyclo[3.3.2.0(4,6)]deca-2,7,9-triene (bullvalene) between 5 and 450 K, J. Chem. Thermodyn., 1980, 12, 967-974. [all data]


Notes

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