Bullvalene
- Formula: C10H10
- Molecular weight: 130.1864
- IUPAC Standard InChI: InChI=1S/C10H10/c1-4-8-9-5-2-7(1)3-6-10(8)9/h1-10H
- IUPAC Standard InChIKey: UKFBVTJTKMSPMI-UHFFFAOYSA-N
- CAS Registry Number: 1005-51-2
- Chemical structure:
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | 262.3 ± 3.3 | kJ/mol | Ccb | Mansson and Sunner, 1981 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -5626.5 ± 3.0 | kJ/mol | Ccb | Mansson and Sunner, 1981 | Corresponding ΔfHºsolid = 262.28 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid,1 bar | 174.66 | J/mol*K | N/A | Falk B., 1980 | DH |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 190.38 | 298.15 | Falk B., 1980 | T = 5 to 450 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mansson and Sunner, 1981
Mansson, M.; Sunner, S.,
Enthalpy of formation and strain energy of bullvalene (tricyclo[3.3.2.04,6]deca-2,7,9-triene); a calorimetric study,
J. Chem. Thermodyn., 1981, 13, 671-675. [all data]
Falk B., 1980
Falk B.,
Heat capacity and thermodynamic properties of tricyclo[3.3.2.0(4,6)]deca-2,7,9-triene (bullvalene) between 5 and 450 K,
J. Chem. Thermodyn., 1980, 12, 967-974. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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