1,3,5-C6H3F3+

• Formula: C₆H₃F₃⁺
• Molecular weight: 132.0827
• CAS Registry Number: 57164-21-3
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B

State:   X

Additional references: Jacox, 1994, page 433; Allan, Maier, et al., 1977; Bondybey and Miller, 1979; Cossart-Magos, Cossart, et al., 1979, 2; Dujardin, Leach, et al., 1980; Maier and Thommen, 1981; Bondybey, Vaughn, et al., 1981

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Allan and Maier, 1975
Allan, M.; Maier, J.P., Emission spectra of the radical cations of hexa-, penta-, tetra-, and tri-fluorobenzenes, Chem. Phys. Lett., 1975, 34, 3, 442, https://doi.org/10.1016/0009-2614(75)85535-7 . [all data]

Miller and Bondybey, 1978
Miller, T.A.; Bondybey, V.E., Laser fluorescence excitation spectra of the 1,3,5-trifluorobenzene radical cation, Chem. Phys. Lett., 1978, 58, 3, 454, https://doi.org/10.1016/0009-2614(78)85074-X . [all data]

Cossart-Magos, Cossart, et al., 1979
Cossart-Magos, C.; Cossart, D.; Leach, S., Emission spectra of seven fluorobenzene cations, Mol. Phys., 1979, 37, 3, 793, https://doi.org/10.1080/00268977900103201 . [all data]

Bondybey, Sears, et al., 1980
Bondybey, V.E.; Sears, T.J.; English, J.H.; Miller, T.A., Low temperature gas phase and matrix studies of the C6H3F3+ and C6H3Cl3+ radical cations, J. Chem. Phys., 1980, 73, 5, 2063, https://doi.org/10.1063/1.440373 . [all data]

Tuckett, 1981
Tuckett, R.P., Fluorescence spectra of fluorobenzene cations excited in a supersonic molecular beam, Chem. Phys., 1981, 58, 2, 151, https://doi.org/10.1016/0301-0104(81)80052-3 . [all data]

Klapstein, Leutwyler, et al., 1984
Klapstein, D.; Leutwyler, S.; Maier, J.P.; Cossart-Magos, C.; Cossart, D.; Leach, S., The, Mol. Phys., 1984, 51, 2, 413, https://doi.org/10.1080/00268978400100281 . [all data]

Tsuchiya, Fujii, et al., 1989
Tsuchiya, Y.; Fujii, M.; Ito, M., Electronic spectra of isolated cations in supersonic jets by mass-selected ion-dip spectroscopy. Cations of benzene, p-difluorobenzene, and 1,3,5-trifluorobenzene, J. Chem. Phys., 1989, 90, 12, 6965, https://doi.org/10.1063/1.456272 . [all data]

Yu, Foster, et al., 1990
Yu, L.; Foster, S.C.; Williamson, J.M.; Miller, T.A., High-resolution electronic spectroscopy of jet-cooled hexafluorobenzene and 1,3,5-trifluorobenzene cations, C6F+6 and C6F3H+3, J. Chem. Phys., 1990, 92, 10, 5794, https://doi.org/10.1063/1.458399 . [all data]

Bondybey, Miller, et al., 1979
Bondybey, V.E.; Miller, T.A.; English, J.H., Laser induced fluorescence spectra of symmetrically substituted trihalobenzene radical cations, J. Chem. Phys., 1979, 71, 3, 1088, https://doi.org/10.1063/1.438474 . [all data]

Sears, Miller, et al., 1980
Sears, T.; Miller, T.A.; Bondybey, V.E., Selectively excited, wavelength resolved emission spectra of gaseous organic ions, J. Chem. Phys., 1980, 72, 12, 6749, https://doi.org/10.1063/1.439164 . [all data]

Bondybey, English, et al., 1983
Bondybey, V.E.; English, J.H.; Miller, T.A., Spectroscopic and dynamical studies of vibrationally unrelaxed fluorescence from halobenzene cations in a neon matrix, J. Phys. Chem., 1983, 87, 8, 1300, https://doi.org/10.1021/j100231a007 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Allan, Maier, et al., 1977
Allan, M.; Maier, J.P.; Marthaler, O., Radative relaxation of the B(π-1)EXCITED ELECTRONIC STATES OF THE RADICAL CATIONS OF REXAFLUOROBENZENE, PENTAFLUOROBENZENE, 1,2,3,4-, 1,2,3,5-, 1,2,4,5-TETRAFLUOROBENZENE, 1,3,5-, 1,2,4-TRIFLUOROBENZENE AND 1,3-DIFLUOROBENZENE, Chem. Phys., 1977, 26, 1, 131, https://doi.org/10.1016/0301-0104(77)87099-7 . [all data]

Bondybey and Miller, 1979
Bondybey, V.E.; Miller, T.A., Laser induced fluorescence from fluorobenzene radical cations in the gas phase, J. Chem. Phys., 1979, 70, 1, 138, https://doi.org/10.1063/1.437231 . [all data]

Cossart-Magos, Cossart, et al., 1979, 2
Cossart-Magos, C.; Cossart, D.; Leach, S., Jahn---Teller effects in substituted benzene cations. II. Gas phase emission spectrum of 1, 3, 5-C6F3D+3 and comparison with 1, 3, 5-C6F3H+3, Chem. Phys., 1979, 41, 3, 345, https://doi.org/10.1016/0301-0104(79)80039-7 . [all data]

Dujardin, Leach, et al., 1980
Dujardin, G.; Leach, S.; Taieb, G., Fluorescence quantum yields and lifetimes of nine fluorobenzene cations. Electronic state relaxation processes, Chem. Phys., 1980, 46, 3, 407, https://doi.org/10.1016/0301-0104(80)85217-7 . [all data]

Maier and Thommen, 1981
Maier, J.P.; Thommen, F., Fluorescence quantum yields and lifetimes of fluorobenzene cations in selected levels of their B and C states determined by photoelectron-photoion coincidence spectroscopy, Chem. Phys., 1981, 57, 319. [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.; Miller, T.A.; English, J.H.; Shiley, R.H., Spectroscopy and decay dynamics of several methyl- and fluorine-substituted benzene radical cations, J. Am. Chem. Soc., 1981, 103, 21, 6303, https://doi.org/10.1021/ja00411a006 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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