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C6F6+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32300 T gas Maier and Thommen, 1981

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21616.16 gas B-X 426 510 Allan and Maier, 1975
Cossart-Magos, Cossart, et al., 1979
Bondybey and Miller, 1979
Sears, Miller, et al., 1981
Tuckett, 1981
Kennedy, Miller, et al., 1986
Yu, Foster, et al., 1990
To = 21553.7 Ne B-X 405 523 Bondybey, Miller, et al., 1980
Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
To = 21372 Ar B-X 418 468 Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
To = 21027 Kr B-X Bondybey and Miller, 1980


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1g 1 1520.0 Ne LF Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
1 1561 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
2 535.5 gas EM LF Cossart-Magos, Cossart, et al., 1979
Sears, Miller, et al., 1981
Kennedy, Miller, et al., 1986
2 538.3 Ne LF Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
2 547 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
a2g 3 603.6 gas LF Kennedy, Miller, et al., 1986
3 629.1 Ne LF Hauge, Kafafi, et al., 1987
a2u 4 203.7 gas LF Kennedy, Miller, et al., 1986
b1u 6 611.0 gas LF Kennedy, Miller, et al., 1986
b2g 7 706.2 gas LF Kennedy, Miller, et al., 1986
8 166.8 gas LF Kennedy, Miller, et al., 1986
b2u 10 274.0 gas LF Kennedy, Miller, et al., 1986
e1g 11 299.0 gas LF Kennedy, Miller, et al., 1986
e1u 14 308.4 gas LF Kennedy, Miller, et al., 1986
e2g 15 1554.0 gas LF Sears, Miller, et al., 1981
15 1552 Ne LF Bondybey and Miller, 1980
15 1603 Ar LF Bondybey, Miller, et al., 1979
16 1187.0 gas LF Sears, Miller, et al., 1981
Hauge, Kafafi, et al., 1987
16 1185.7 Ne LF Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
16 1196 Ar LF Bondybey, Miller, et al., 1979
17 421.86 gas EM LF Cossart-Magos, Cossart, et al., 1979
Bondybey and Miller, 1979
Sears, Miller, et al., 1981
Kennedy, Miller, et al., 1986
Yu, Foster, et al., 1990
17 424.4 Ne LF Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
17 428 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
18 262.02 gas EM LF Cossart-Magos, Cossart, et al., 1979
Bondybey and Miller, 1979
Sears, Miller, et al., 1981
Kennedy, Miller, et al., 1986
Yu, Foster, et al., 1990
18 264.4 Ne LF Bondybey and Miller, 1980
Hauge, Kafafi, et al., 1987
18 270 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
e2u 19 573.8 gas LF Kennedy, Miller, et al., 1986
20 114.1 gas LF Kennedy, Miller, et al., 1986

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1g 2 556 gas UV LF Cossart-Magos, Cossart, et al., 1979
Sears, Miller, et al., 1981
Tuckett, 1981
2 554 Ne LF Bondybey and Miller, 1980
2 557 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
e2g 15 1698 Ne LF Bondybey and Miller, 1980
16 1226 Ne LF Bondybey and Miller, 1980
17 406 gas UV EF Sears, Miller, et al., 1981
Tuckett, 1981
17 417 Ne LF Bondybey and Miller, 1980
17 444 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979
18 284 gas UV LF Cossart-Magos, Cossart, et al., 1979
Sears, Miller, et al., 1981
Tuckett, 1981
18 289 Ne LF Bondybey and Miller, 1980
18 300 Ar LF Bondybey, English, et al., 1978
Bondybey, Miller, et al., 1979

Additional references: Jacox, 1994, page 438; Allan, Maier, et al., 1977; Bondybey, Vaughn, et al., 1981; Winkoun, Chapoulard, et al., 1984

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier and Thommen, 1981
Maier, J.P.; Thommen, F., Fluorescence quantum yields and lifetimes of fluorobenzene cations in selected levels of their B and C states determined by photoelectron-photoion coincidence spectroscopy, Chem. Phys., 1981, 57, 319. [all data]

Allan and Maier, 1975
Allan, M.; Maier, J.P., Emission spectra of the radical cations of hexa-, penta-, tetra-, and tri-fluorobenzenes, Chem. Phys. Lett., 1975, 34, 3, 442, https://doi.org/10.1016/0009-2614(75)85535-7 . [all data]

Cossart-Magos, Cossart, et al., 1979
Cossart-Magos, C.; Cossart, D.; Leach, S., Emission spectra of seven fluorobenzene cations, Mol. Phys., 1979, 37, 3, 793, https://doi.org/10.1080/00268977900103201 . [all data]

Bondybey and Miller, 1979
Bondybey, V.E.; Miller, T.A., Laser induced fluorescence from fluorobenzene radical cations in the gas phase, J. Chem. Phys., 1979, 70, 1, 138, https://doi.org/10.1063/1.437231 . [all data]

Sears, Miller, et al., 1981
Sears, T.; Miller, T.A.; Bondybey, V.E., Laser excitation and emission spectra of the hexafluorobenzene cation in the gas phase, J. Am. Chem. Soc., 1981, 103, 2, 326, https://doi.org/10.1021/ja00392a014 . [all data]

Tuckett, 1981
Tuckett, R.P., Fluorescence spectra of fluorobenzene cations excited in a supersonic molecular beam, Chem. Phys., 1981, 58, 2, 151, https://doi.org/10.1016/0301-0104(81)80052-3 . [all data]

Kennedy, Miller, et al., 1986
Kennedy, R.A.; Miller, T.A.; Scharf, B., Novel effects in the laser induced fluorescence spectrum of C6F+6, J. Chem. Phys., 1986, 85, 3, 1336, https://doi.org/10.1063/1.451221 . [all data]

Yu, Foster, et al., 1990
Yu, L.; Foster, S.C.; Williamson, J.M.; Miller, T.A., High-resolution electronic spectroscopy of jet-cooled hexafluorobenzene and 1,3,5-trifluorobenzene cations, C6F+6 and C6F3H+3, J. Chem. Phys., 1990, 92, 10, 5794, https://doi.org/10.1063/1.458399 . [all data]

Bondybey, Miller, et al., 1980
Bondybey, V.E.; Miller, T.A.; English, J.H., Observation of Slow Vibrational Relaxation in Halogenated Benzene Radical Cations in Rare-Gas Solids, Phys. Rev. Lett., 1980, 44, 20, 1344, https://doi.org/10.1103/PhysRevLett.44.1344 . [all data]

Bondybey and Miller, 1980
Bondybey, V.E.; Miller, T.A., Absorption and laser induced fluorescence spectra of C6F6+ inert gas matrices, J. Chem. Phys., 1980, 73, 7, 3053, https://doi.org/10.1063/1.440563 . [all data]

Hauge, Kafafi, et al., 1987
Hauge, R.H.; Kafafi, Z.H.; Margrave, J.L., Physics and Chemistry of Small Clusters, P. Jena, B.K. Rao, and S.N. Khanna, Eds., p.787, Plenum, 1987. [all data]

Bondybey, English, et al., 1978
Bondybey, V.E.; English, J.H.; Miller, T.A., Laser fluorescence spectra of the hexafluorobenzene cation in solid argon, J. Am. Chem. Soc., 1978, 100, 16, 5251, https://doi.org/10.1021/ja00484a079 . [all data]

Bondybey, Miller, et al., 1979
Bondybey, V.E.; Miller, T.A.; English, J.H., Matrix laser fluorescence spectra of several fluorobenzene radical cations, J. Am. Chem. Soc., 1979, 101, 5, 1248, https://doi.org/10.1021/ja00499a033 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Allan, Maier, et al., 1977
Allan, M.; Maier, J.P.; Marthaler, O., Radative relaxation of the B(«pi»-1)EXCITED ELECTRONIC STATES OF THE RADICAL CATIONS OF REXAFLUOROBENZENE, PENTAFLUOROBENZENE, 1,2,3,4-, 1,2,3,5-, 1,2,4,5-TETRAFLUOROBENZENE, 1,3,5-, 1,2,4-TRIFLUOROBENZENE AND 1,3-DIFLUOROBENZENE, Chem. Phys., 1977, 26, 1, 131, https://doi.org/10.1016/0301-0104(77)87099-7 . [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.; Miller, T.A.; English, J.H.; Shiley, R.H., Spectroscopy and decay dynamics of several methyl- and fluorine-substituted benzene radical cations, J. Am. Chem. Soc., 1981, 103, 21, 6303, https://doi.org/10.1021/ja00411a006 . [all data]

Winkoun, Chapoulard, et al., 1984
Winkoun, D.; Chapoulard, D.; Dujardin, G.; Leach, S., Vibrational dependence of electronic nonradiative processes in the state of and, Can. J. Phys., 1984, 62, 12, 1361, https://doi.org/10.1139/p84-183 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References