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Sulfur chloride


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21650 gas 378 481 McGrath, 1960
Donovan, Husain, et al., 1968
Chiu, Pan, et al., 1986
To = 21925 U Ar 389 456 Wight and Andrews, 1978


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 Stretch 480 gas AB Chiu, Pan, et al., 1986
1 Stretch 491 ± 20 Ar AB Wight and Andrews, 1978
3 Stretch 407 gas AB Chiu, Pan, et al., 1986

State:   A


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 SS stretch 630 gas LF Chiu and Chang, 1994
Chang, 1995
2 Bend 249 gas LF Chiu and Chang, 1994
Chang, 1995
3 SCl stretch 554 gas LF Chiu and Chang, 1994
Chang, 1995

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 SS stretch 662 ± 3 gas AB LF Chiu, Pan, et al., 1986
Chiu and Chang, 1994
Chang, 1995
1 SS stretch 665 Ar IR Vahl and Feuerhahn, 1979
2 Bend 196 gas Ra LF Chiu and Chang, 1994
Chang, 1995
3 SCl stretch 450 gas Ra LF Chiu and Chang, 1994
Chang, 1995
3 SCl stretch 404 Ar IR Vahl and Feuerhahn, 1979

Additional references: Jacox, 1994, page 111; Jacox, 1998, page 205; Fujitake and Hirota, 1994

Notes

UUpper bound
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McGrath, 1960
McGrath, W.D., The Production of Vibrationally Excited S2 in the Isothermal Flash Photolysis of S2Cl2, J. Chem. Phys., 1960, 33, 1, 297, https://doi.org/10.1063/1.1731104 . [all data]

Donovan, Husain, et al., 1968
Donovan, R.J.; Husain, D.; Jackson, P.T., Transient species in the photolysis of sulphur monochloride, including S2(a 1? g )., Trans. Faraday Soc., 1968, 64, 1798, https://doi.org/10.1039/tf9686401798 . [all data]

Chiu, Pan, et al., 1986
Chiu, C.L.; Pan, S.C.; Ni, C.K., Recognition of the violet system of S2Cl in the pyrolysis of S2Cl2, J. Chem. Phys., 1986, 85, 1, 10, https://doi.org/10.1063/1.451648 . [all data]

Wight and Andrews, 1978
Wight, C.A.; Andrews, L., Matrix reactions of dichlorodisulfane with alkali metals, J. Mol. Spectrosc., 1978, 72, 3, 342, https://doi.org/10.1016/0022-2852(78)90134-0 . [all data]

Chiu and Chang, 1994
Chiu, C.-L.; Chang, H., Spectrochim. Acta, 1994, 50A, 2239. [all data]

Chang, 1995
Chang, C.L. ChiuadnH., J. Chin. Chem. Soc. (Taipei), 1995, 42, 19. [all data]

Vahl and Feuerhahn, 1979
Vahl, G.; Feuerhahn, M., J. Chem. Res., 1979, Synop., 237. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Fujitake and Hirota, 1994
Fujitake, M.; Hirota, E., The microwave spectrum of the ClS, Can. J. Phys., 1994, 72, 11-12, 1043, https://doi.org/10.1139/p94-136 . [all data]


Notes

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