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HO2CH2OH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3647.8 s gas IR Niki, Maker, et al., 1980
Fry, Matthews, et al., 2006
OH stretch 3598.1 m s gas IR Niki, Maker, et al., 1980
Fry, Matthews, et al., 2006
CH stretch 2947.2 w m gas IR Su, Calvert, et al., 1979
Fry, Matthews, et al., 2006
OOH bend 1344.9 s gas IR Su, Calvert, et al., 1979
Fry, Matthews, et al., 2006
CO stretch 1049.5 vs gas IR Su, Calvert, et al., 1979
Fry, Matthews, et al., 2006
OO stretch 820 T gas IR Su, Calvert, et al., 1979

Additional references: Jacox, 1994, page 379; Bauerle and Moortgat, 1999

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Niki, Maker, et al., 1980
Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P., Further IR spectroscopic evidence for the formation of CH2(OH)OOH in the gas-phase reaction of HO2 with CH2O, Chem. Phys. Lett., 1980, 75, 3, 533, https://doi.org/10.1016/0009-2614(80)80571-9 . [all data]

Fry, Matthews, et al., 2006
Fry, J.L.; Matthews, J.; Lane, J.R.; Roehl, C.M.; Sinha, A.; Kjaergaard, H.G.; Wennberg, P.O., OH-Stretch Vibrational Spectroscopy of Hydroxymethyl Hydroperoxide, J. Phys. Chem. A, 2006, 110, 22, 7072, https://doi.org/10.1021/jp0612127 . [all data]

Su, Calvert, et al., 1979
Su, F.; Calvert, J.G.; Shaw, J.H.; Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P., Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde, Chem. Phys. Lett., 1979, 65, 2, 221, https://doi.org/10.1016/0009-2614(79)87053-0 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Bauerle and Moortgat, 1999
Bauerle, S.; Moortgat, G.K., Absorption cross-sections of HOCH2OOH vapor between 205 and 360 nm at 298 K, Chem. Phys. Lett., 1999, 309, 1-2, 43, https://doi.org/10.1016/S0009-2614(99)00652-1 . [all data]


Notes

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