- Formula: C18H15Bi
- Molecular weight: 440.2921
- IUPAC Standard InChI:
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- IUPAC Standard InChIKey: ZHXAZZQXWJJBHA-UHFFFAOYSA-N
- CAS Registry Number: 603-33-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
- Other names: Bismuth triphenyl; Triphenylbismuth; Triphenylbismuthine; (C6H5)3Bi; Aerotex; Trifenylbismutin
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
|Tfus||351.5||K||N/A||Forward, Bowden, et al., 1949||Uncertainty assigned by TRC = 0.5 K; TRC|
|Tfus||350.15||K||N/A||Smith and Andrews, 1931||Uncertainty assigned by TRC = 1. K; with Hg thermometer; TRC|
|Tfus||346.65||K||N/A||Smith and Andrews, 1931||Uncertainty assigned by TRC = 1. K; with thermocouple; TRC|
|subH°||110.9 ± 8.4||kJ/mol||N/A||Pilcher and Skinner, 1983||See also Steele, 1979.; AC|
|subH°||110.9 ± 8.4||kJ/mol||CC-SB||Skinner H.A., 1964||MS|
Go To: Top, Phase change data, Notes
Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the group V elements. 2. Triphenylbismuth and the Ph-Bi mean bond-dissociation energy, J. Chem. Thermodynam., 1979, 11, 187-192. [all data]
Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]
Go To: Top, Phase change data, References
- Symbols used in this document:
Tfus Fusion (melting) point subH° Enthalpy of sublimation at standard conditions
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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