Bismuthine, triphenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus351.5KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tfus350.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1. K; with Hg thermometer; TRC
Tfus346.65KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1. K; with thermocouple; TRC
Quantity Value Units Method Reference Comment
Δsub26.5 ± 2.0kcal/molN/APilcher and Skinner, 1983See also Steele, 1979.; AC
Δsub26.5 ± 2.0kcal/molCC-SBSkinner H.A., 1964MS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Steele, 1979
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the group V elements. 2. Triphenylbismuth and the Ph-Bi mean bond-dissociation energy, J. Chem. Thermodynam., 1979, 11, 187-192. [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]


Notes

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