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1,4-Butanediol

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-426.0 ± 5.7kJ/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989
Deltafgas-427. ± 3.kJ/molCcbGardner and Hussain, 1972 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-505.3 ± 5.7kJ/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Deltafliquid-503. ± 2.kJ/molCcbGardner and Hussain, 1972ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2495.5 ± 5.7kJ/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; Corresponding «DELTA»fliquid = -507.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2499.9 ± 2.0kJ/molCcbGardner and Hussain, 1972Corresponding «DELTA»fliquid = -503.25 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid223.4J/mol*KN/ANistratov, Babinkov, et al., 1979DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
200.1298.15Nistratov, Babinkov, et al., 1979T = 5 to 320 K.; DH
178.297.79Petit and TerMinassian, 1974T = 297 to 470 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil503.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil502.88KN/AMarkovnik, Sachek, et al., 1981Uncertainty assigned by TRC = 0.05 K; TRC
Tboil501.15KN/AMellan, 1962Uncertainty assigned by TRC = 2. K; TRC
Tboil503.15KN/AMellan, 1962Uncertainty assigned by TRC = 2. K; TRC
Tboil501.15KN/AClendenning, Macdonald, et al., 1950Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus300. ± 40.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple289.9KN/AKnauth and Sabbah, 1990, 2Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple293.58KN/AVasil'ev and Petrov, 1984Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple293.38KN/ANistratov, Babinkov, et al., 1979, 2Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple293.58KN/ANistratov, Babinkov, et al., 1979, 2Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Tc727.KN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Pc62.20barN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 1.50 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap78. ± 3.kJ/molAVGN/AAverage of 8 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
393.20.013Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
72.395.AStephenson and Malanowski, 1987Based on data from 380. - 510. K.; AC
77. ± 2.419.VGardner and Hussain, 1972ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
18.700293.58Nistratov, Babinkov, et al., 1979DH
18.7293.6Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
63.72293.58Nistratov, Babinkov, et al., 1979DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of intra- and intermolecular bonds in «omega»-alkanediols (II) Thermochemical study of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol at 298.15K, Struct. Chem., 1990, 1, 43-46. [all data]

Knauth and Sabbah, 1989
Knauth, P.; Sabbah, R., Combustion calorimetry on milligram samples of liquid substances with a CRMT rocking bomb calorimeter. Application to the study of «omega»-alkanediol at 298.15 K, J. Chem. Thermodyn., 1989, 21, 203-210. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Nistratov, Babinkov, et al., 1979
Nistratov, V.P.; Babinkov, A.G.; Shvetsova, K.G.; Lapteva, S.A., Heat capacity and termodynamic functions of tetramethyleneglycol, Termodin. Org. Soedin., 1979, (8), 33-36. [all data]

Petit and TerMinassian, 1974
Petit, J.C.; TerMinassian, L., Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, J. Chem. Thermodynam., 1974, 6, 1139-1152. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Markovnik, Sachek, et al., 1981
Markovnik, V.S.; Sachek, A.I.; Peshchenko, A.D.; Shvaro, O.V.; Andreyevskii, D.N., Vapor pressure of some glycols in Terodinamika Organ. Soedinenii., Gorkii, p 54, 1981. [all data]

Mellan, 1962
Mellan, I., Polyhydric Alcohols, Spartan Books: Washington, DC, 1962. [all data]

Clendenning, Macdonald, et al., 1950
Clendenning, K.A.; Macdonald, F.J.; Wright, D.E., Effects of position isomerism on the physical properties of glycols, Can. J. Res., Sect. B, 1950, 28, 608-22. [all data]

Knauth and Sabbah, 1990, 2
Knauth, P.; Sabbah, R., Can. J. Chem., 1990, 68, 731. [all data]

Vasil'ev and Petrov, 1984
Vasil'ev, I.A.; Petrov, V.M., Thermodynamic Properties of Oxygen-containing Organic Compounds, Handbook, Soedinenii: Khimya, Leningrad, p 240, 1984. [all data]

Nistratov, Babinkov, et al., 1979, 2
Nistratov, V.P.; Babinkov, A.G.; Shvetsova, K.G.; Kapteva, S.A., Heat capacity and thermodynamic functions of tetramethylene glycol., Termodin. Org. Soedin., 1979, No. 8, 33. [all data]

Wilson, Wilson, et al., 1996
Wilson, L.C.; Wilson, H.L.; Wilding, W.V.; Wilson, G.M., Critical Point Measurements for Fourteen Compounds by a Static Method and a Flow Method, J. Chem. Eng. Data, 1996, 41, 1252-4. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References