2-Silaisobutene

• Formula: C₃H₈Si
• Molecular weight: 72.1811
• IUPAC Standard InChI: InChI=1S/C3H8Si/c1-4(2)3/h1H2,2-3H3 Copy

  
• IUPAC Standard InChIKey: ZIOQFHFYVWYPJP-UHFFFAOYSA-N Copy
• CAS Registry Number: 4112-23-6
• Chemical structure:
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• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C₃H₇Si^- +  =

By formula: C₃H₇Si^- + H⁺ = C₃H₈Si

(CAS Reg. No. 54711-92-1 • 4294967295) +  = CAS Reg. No. 54711-92-1

By formula: (CAS Reg. No. 54711-92-1 • 4294967295C₃H₈Si) + C₃H₈Si = CAS Reg. No. 54711-92-1

 +  = ( • )

By formula: F^- + C₃H₈Si = (F^- • C₃H₈Si)

 +  = ( • )

By formula: Fe⁺ + C₃H₈Si = (Fe⁺ • C₃H₈Si)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, DePuy, et al., 1986
Damrauer, R.; DePuy, C.H.; Davidson, I.M.T.; Hughes, K.J., Gas phase ion chemistry of dimethylsilene, Organometallics, 1986, 5, 2050. [all data]

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]

Allison and McMahon, 1990
Allison, C.E.; McMahon, T.B., How Strong is the Si=C Bond in Fluoro- and Methyl Substituted Silaethylenes? An Experimental Determination of Pi Bond Strengths, J. Am. Chem. Soc., 1990, 112, 5, 1672, https://doi.org/10.1021/ja00161a002 . [all data]

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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