Maleic anhydride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-470.41 ± 0.71kJ/molCcbWilhoit and Shiao, 1964ALS
Δfsolid-469.6 ± 0.3kJ/molCcbParks, Mosley, et al., 1950ALS
Quantity Value Units Method Reference Comment
Δcsolid-1389.5 ± 0.67kJ/molCcbWilhoit and Shiao, 1964Corresponding Δfsolid = -470.41 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-1390.3 ± 0.71kJ/molCcbParks, Mosley, et al., 1950Corresponding Δfsolid = -469.57 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
119.9300.DeWit, DeKruif, et al., 1983T = 90 to 350 K. Linearly extrapolated.; DH
123.2310.DeWit, Offringa, et al., 1983T = 300 to 450 K.; DH
67.4298.15Marchidan and Ciopec, 1978T = 298 to 480 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wilhoit and Shiao, 1964
Wilhoit, R.C.; Shiao, D., Thermochemistry of biologically important compounds. Heats of combustion of solid organic acids., J. Chem. Eng. Data, 1964, 9, 595-599. [all data]

Parks, Mosley, et al., 1950
Parks, G.S.; Mosley, J.R.; Peterson, P.V., Jr., Heats of combustion and formation of some organic compounds containing oxygen, J. Chem. Phys., 1950, 18, 152. [all data]

DeWit, DeKruif, et al., 1983
DeWit, H.G.M.; DeKruif, C.G.; Van Miltenburg, J.C., Thermodynamic properties of molecular organic crystals containing organic crystals containing nitrogen, oxygen, and sulfur. II. Molar heat capacities of eight compounds by adiabatic calorimetry, J. Chem. Thermodynam., 1983, 15, 891-902. [all data]

DeWit, Offringa, et al., 1983
DeWit, H.G.M.; Offringa, J.C.A.; De Kruif, C.G.; Van Miltenburg, J.C., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen and sulfur. III. Molar heat capacities measured by differential scanning calorimetry, Thermochim. Acta, 1983, 65, 43-51. [all data]

Marchidan and Ciopec, 1978
Marchidan, D.I.; Ciopec, M., Thermodynamic properties of maleic, trimellitic and pyromellitic anhydrides, Rev. Roum. Chim., 1978, 23, 19-29. [all data]


Notes

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