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Tert-butyllithium tetramer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
6.2 ± 0.25DERMcLean, Murray, et al., 1978LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
LiCH3+11.0 ± 0.50?PIMcLean, Murray, et al., 1978LLK
C2H5+11. ± 0.5?PIMcLean, Murray, et al., 1978LLK
C3H6+11. ± 0.50?PIMcLean, Murray, et al., 1978LLK
C4H9+11. ± 0.50?PIMcLean, Murray, et al., 1978LLK
C4H9Li2+11.7?EIVitkovskii and Bravo-Zhivotovskii, 1985LBLHLM
Li2C4H9+8.1 ± 0.25?PIMcLean, Murray, et al., 1978LLK
Li4C4H9+8.1 ± 0.25?PIMcLean, Murray, et al., 1978LLK
C8H18Li3+12.0?EIVitkovskii and Bravo-Zhivotovskii, 1985LBLHLM
Li4C8H18+8.1 ± 0.25?PIMcLean, Murray, et al., 1978LLK
C12H27Li4+8.1C4H9EIVitkovskii and Bravo-Zhivotovskii, 1985LBLHLM
Li4C12H27+6.2 ± 0.25?PIMcLean, Murray, et al., 1978LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McLean, Murray, et al., 1978
McLean, W.; Murray, P.T.; Baer, T.; Jarnagin, R.C., Dissociative photoionization of t-butyl-lithium, J. Chem. Phys., 1978, 69, 2715. [all data]

Vitkovskii and Bravo-Zhivotovskii, 1985
Vitkovskii, V.Yu.; Bravo-Zhivotovskii, D.A., Mass spectra of (trimethylsilyl) lithium and tert-butyllithium, J. Gen. Chem. USSR, 1985, 56, 853, In original 968. [all data]


Notes

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