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1,4-Dioxane-2,5-dione

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-615.6kJ/molN/ALebedev, Kulagina, et al., 1988Value computed using «DELTA»fHsolid° value of -704.0±0.6 kj/mol from Lebedev, Kulagina, et al., 1988 and «DELTA»subH° value of 88.4 kj/mol from Kiparisova, Bykova, et al., 1977.; DRB
Deltafgas-612.0 ± 1.4kJ/molCcbKiparisova, Bykova, et al., 1977ALS
Deltafgas-611.9kJ/molN/ALebedev, Evstropov, et al., 1977Value computed using «DELTA»fHsolid° value of -700.3±0.6 kj/mol from Lebedev, Evstropov, et al., 1977 and «DELTA»subH° value of 88.4 kj/mol from Kiparisova, Bykova, et al., 1977.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-704.0 ± 0.6kJ/molCcbLebedev, Kulagina, et al., 1988see Lebedev, Yevstropov, et al., 1978 and Evstropov, Belov, et al., 1978; ALS
Deltafsolid-700.4 ± 0.59kJ/molCcbKiparisova, Bykova, et al., 1977crystal phase; ALS
Deltafsolid-700.3 ± 0.6kJ/molCcbLebedev, Evstropov, et al., 1977ALS
Quantity Value Units Method Reference Comment
Deltacsolid-1441.8 ± 0.6kJ/molCcbLebedev, Kulagina, et al., 1988see Lebedev, Yevstropov, et al., 1978 and Evstropov, Belov, et al., 1978; Corresponding «DELTA»fsolid = -703.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-1445.4 ± 0.59kJ/molCcbKiparisova, Bykova, et al., 1977crystal phase; Corresponding «DELTA»fsolid = -700.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-1445.4 ± 0.6kJ/molCcbLebedev, Evstropov, et al., 1977Corresponding «DELTA»fsolid = -700.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar157.23J/mol*KN/ALebedev, Kulagina, et al., 1988crystaline, II phase; DH
solid,1 bar157.2J/mol*KN/ALebedev, Yevstropov, et al., 1978, 2crystaline, II phase; DH
solid,1 bar157.2J/mol*KN/ALebedev, Evstropov, et al., 1977, 2crystaline, II phase; DH
solid,1 bar157.2J/mol*KN/AEvstropov, Belov, et al., 1978, 2crystaline, II phase; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
133.28298.15Lebedev, Kulagina, et al., 1988crystaline, II phase; T = 13.8 to 400 K.; DH
133.2298.15Evstropov, Belov, et al., 1978, 2crystaline, II phase; T = 14 to 350 K. Complete data deposited in VINITI, No. 2144-77, 2 June 1977.; DH
133.3298.15Lebedev, Yevstropov, et al., 1978, 2crystaline, II phase; T = 13.8 to 550 K.; DH
133.3298.15Lebedev, Evstropov, et al., 1977, 2crystaline, II phase; T = 13.8 to 550 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple356.2KN/ALebedev, Kulagina, et al., 1988, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple356.2KN/AEvstropov, Belov, et al., 1978, 3Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltasub88.4 ± 0.8kJ/molCKiparisova, Bykova, et al., 1977crystal phase; ALS
Deltasub88.4kJ/molN/AKiparisova, Bykova, et al., 1977DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
50.4391.AStephenson and Malanowski, 1987Based on data from 376. - 513. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
376. - 513.5.159222383.101-51.139Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
14.8356.2ACDomalski and Hearing, 1996See also Lebedev, Kulagina, et al., 1988.; AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
5.82312.1Domalski and Hearing, 1996CAL
41.55356.2

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.8400312.1crystaline, IIcrystaline, ILebedev, Kulagina, et al., 1988DH
14.800356.2crystaline, IliquidLebedev, Kulagina, et al., 1988DH
1.810312.1crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1978, 2DH
14.800356.2crystaline, IliquidLebedev, Yevstropov, et al., 1978, 2DH
1.840312.1crystaline, IIcrystaline, ILebedev, Evstropov, et al., 1977, 2DH
14.800356.2crystaline, IliquidLebedev, Evstropov, et al., 1977, 2DH
1.810312.1crystaline, IIcrystaline, IEvstropov, Belov, et al., 1978, 2DH
14.800356.2crystaline, IliquidEvstropov, Belov, et al., 1978, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
5.90312.1crystaline, IIcrystaline, ILebedev, Kulagina, et al., 1988DH
41.49356.2crystaline, IliquidLebedev, Kulagina, et al., 1988DH
5.80312.1crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1978, 2DH
41.5356.2crystaline, IliquidLebedev, Yevstropov, et al., 1978, 2DH
5.90312.1crystaline, IIcrystaline, ILebedev, Evstropov, et al., 1977, 2DH
41.5356.2crystaline, IliquidLebedev, Evstropov, et al., 1977, 2DH
5.80312.1crystaline, IIcrystaline, IEvstropov, Belov, et al., 1978, 2DH
41.5356.2crystaline, IliquidEvstropov, Belov, et al., 1978, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 1992

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Kulagina, et al., 1988
Lebedev, B.V.; Kulagina, T.G.; Smirnova, N.N., Thermodynamics of 4-methylcyclo-hexene, glycollide, and 1,1,3,3,5,5-hexaethylcyclotrisiloxane from 13.4 to 400 K, J. Chem. Thermodyn., 1988, 20, 1383-1396. [all data]

Kiparisova, Bykova, et al., 1977
Kiparisova, E.G.; Bykova, T.A.; Lebedev, B.V., Standard enthalpy of formation and combustion of glycolide and polyglycolide, Vses. Konf. Kalorim. Rasshir. Tezisy Dokl. 7th, 1977, 1, 106-110. [all data]

Lebedev, Evstropov, et al., 1977
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, E.G.; Lyudvig, R.B.; Sanina, G.S., Thermodynamics of the polymerization of glycolide, Dokl. Akad. Nauk SSSR, 1977, 236, 925-928. [all data]

Lebedev, Yevstropov, et al., 1978
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Ye.G.; Belov, V.I., The thermodynamics of glycollide, polyglycollide and of polymerization of glycollide in the temperature range of 0-550°K, Polym. Sci. USSR (Engl. Transl.), 1978, 20, 32-42. [all data]

Evstropov, Belov, et al., 1978
Evstropov, A.A.; Belov, V.I.; Lebedev, B.V.; Kiparisova, E.G.; Bykova, T.A., Thermodynamic properties of glycolide in the temperature range 0-400 K, Russ. J. Phys. Chem. (Engl. Transl.), 1978, 52, 136. [all data]

Lebedev, Yevstropov, et al., 1978, 2
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Y.G.; Belov, V.I., The thermodynamics of glycollide, polyglycollide and of polymerization of glycollide in the temperature range of 0-550°K, Vysokomol. Soedin., 1978, A20, 29-37. [all data]

Lebedev, Evstropov, et al., 1977, 2
Lebedev, B.V.; Evstropov, A.A.; Milov, V.I.; Sladkov, A.M.; Vasneva, N.A., Thermodynamic properties of polyvinylenediphenylsilane in the range 13-334, Zhur. Fiz. Khim., 1977, 51, 275. [all data]

Evstropov, Belov, et al., 1978, 2
Evstropov, A.A.; Belov, V.I.; Lebedev, B.V.; Kiparisova, Y.G.; Bykova, T.A., Thermodynamic properties of glycolide in the 0-400 K range, Zhur. Fiz. Khim., 1978, 52, 242. [all data]

Lebedev, Kulagina, et al., 1988, 2
Lebedev, B.V.; Kulagina, T.G.; Smirnova, N.N., Thermodynamics of 4-methylcyclohexene, glycollide, and 1,1,3,3,5,5-hexaethylcyclotrisiloxane from 13.4 to 400 K, J. Chem. Thermodyn., 1988, 20, 1383. [all data]

Evstropov, Belov, et al., 1978, 3
Evstropov, A.A.; Belov, V.I.; Lebedev, B.V.; Kiparisova, E.G., Zh. Fiz. Khim., 1978, 52, 243. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References