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p-Diacetylbenzene diethyl ketal

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-793.6 ± 9.0kJ/molCcbKaryakin, Sapozhnikov, et al., 1978see Karyakin, Sapozhnikov, et al., 1977

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-905.8 ± 7.0kJ/molCcbKaryakin, Sapozhnikov, et al., 1978see Karyakin, Sapozhnikov, et al., 1977; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-10465. ± 5.kJ/molCcbKaryakin, Sapozhnikov, et al., 1978see Karyakin, Sapozhnikov, et al., 1977; Corresponding «DELTA»fsolid = -906. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar493.8J/mol*KN/AKaryakin, Rabinovich, et al., 1978DH
solid,1 bar493.8J/mol*KN/AKaryakin, Sapozhnikov, et al., 1978, 2DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
462.0298.15Karyakin, Rabinovich, et al., 1978T = 5 to 340 K.; DH
460.300.Karyakin, Sapozhnikov, et al., 1978, 2T = 5 to 326.1 K. Data given graphically. Value estimated from graph.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karyakin, Sapozhnikov, et al., 1978
Karyakin, N.V.; Sapozhnikov, V.N.; Teplyakov, M.M.; Chebotarev, V.P., The thermodynamics of polycondensation of the ethyl ketals of acetophenone and «rho»-diacetylbenzene, Polym. Sci. USSR, 1978, 20, 2191-2199. [all data]

Karyakin, Sapozhnikov, et al., 1977
Karyakin, N.V.; Sapozhnikov, V.N.; Teplyakov, M.M.; Chebotarev, V.P., Thermodynamics of the synthesis of polyphenylene based on ethyl ketals of acetophenone and p-diacetylbenzene, Dokl. Phys. Chem. (Engl. Transl.), 1977, 237, 867-870. [all data]

Karyakin, Rabinovich, et al., 1978
Karyakin, N.V.; Rabinovich, I.B.; Nistratov, V.P., Heat capacity and thermodynamic functions of p-diacetylbenzene diethyl ketal, Termodin. Org. Soedin., 1978, (7), 12-16. [all data]

Karyakin, Sapozhnikov, et al., 1978, 2
Karyakin, N.V.; Sapozhnikov, V.N.; Teplyakov, M.M.; Chebotarev, V.P., The thermodynamics of polycondensation of the ethyl ketals of acetophenone and p-diacetylbenzene, Vysokomol. Soedin., 1978, A20, 1950-1956. [all data]


Notes

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