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Bromodifluoromethyl radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

View reactions leading to CBrF2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
13. ± 1.DERLangford and Harris, 1990

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CF stretch 1198 Ar IR Jacox, 1978
Prochaska and Andrews, 1978
CF stretch 1138 Ar IR Jacox, 1978
Prochaska and Andrews, 1978
CBr stretch 684 Ar IR Jacox, 1978
Prochaska and Andrews, 1978

Additional references: Jacox, 1994, page 216


References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Langford and Harris, 1990
Langford, M.L.; Harris, F.M., Experimental determination of the energies required to ionize the ions CFCl+, CFBr+, CClBr+, CF2Cl+, CF2Br+, CCl2F+, CBr2F+, and CBr2Cl+, Int. J. Mass Spectrom. Ion Phys., 1990, 96, 111. [all data]

Jacox, 1978
Jacox, M.E., Matrix isolation study of the photolysis of CF2Br2. Infrared spectrum of the CF2Br Free radical, Chem. Phys. Lett., 1978, 53, 1, 192, https://doi.org/10.1016/0009-2614(78)80422-9 . [all data]

Prochaska and Andrews, 1978
Prochaska, F.T.; Andrews, L., Matrix photoionization studies of trifluoromethyl halide systems. Infrared spectra of the CF3+, CF2X+, and CF3X+ cations in solid argon, J. Am. Chem. Soc., 1978, 100, 7, 2102, https://doi.org/10.1021/ja00475a021 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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