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Ferrocene, formyl-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub89.7 ± 5.1kJ/molMELousada, Pinto, et al., 2008 
Deltasub87.9 ± 3.5kJ/molMELousada, Pinto, et al., 2008 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
89.9 ± 5.1305.MELousada, Pinto, et al., 2008Based on data from 302. - 312. K.
87.3 ± 3.5310.MELousada, Pinto, et al., 2008Based on data from 302. - 312. K.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
2.5397.2DSCLousada, Pinto, et al., 2008 
2.76397.6ACKaneko and Sorai, 2007Based on data from 13. - 405. K.
2.05396.7N/ADaniel, Leadbetter, et al., 1978 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lousada, Pinto, et al., 2008
Lousada, Cláudio M.; Pinto, Susana S.; Canongia Lopes, José N.; Minas da Piedade, M. Fátima; Diogo, Hermínio P.; Minas da Piedade, Manuel E., Experimental and Molecular Dynamics Simulation Study of the Sublimation and Vaporization Energetics of Iron Metalocenes. Crystal Structures of Fe(«eta» 5 -C 5 H 4 CH 3 ) 2 and Fe[(«eta» 5 -(C 5 H 5 )(«eta» 5 -C 5 H 4 CHO)], J. Phys. Chem. A, 2008, 112, 13, 2977-2987, https://doi.org/10.1021/jp7107818 . [all data]

Kaneko and Sorai, 2007
Kaneko, Y.; Sorai, M., Heat capacity and phase transitions of the plastic crystal formylferrocene, Phase Transitions, 2007, 80, 6-7, 517-528, https://doi.org/10.1080/01411590701339401 . [all data]

Daniel, Leadbetter, et al., 1978
Daniel, M.F.; Leadbetter, Alan J.; Meads, R.E.; Parker, W.G., Structure of the ferrocene carboxaldehyde mesophase by X-ray diffraction and M«65533»ssbauer spectroscopy, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 456, https://doi.org/10.1039/f29787400456 . [all data]


Notes

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